The visible- light photocatalytic degradation of ibuprofen by the CuS-Fe3O4/RGO catalyst

被引:12
作者
Pirsaheb, Meghdad [1 ]
Hossaini, Hiwa [1 ]
Fatahi, Nazir [1 ]
Jafari, Zeinab [1 ,2 ]
Jafari, Fataneh
Motlagh, Reza Jafari [3 ,4 ]
机构
[1] Kermanshah Univ Med Sci, Res Ctr Environm Determinants Hlth RCEDH, Kermanshah, Iran
[2] Kermanshah Univ Med Sci, Students Res Comm, Kermanshah, Iran
[3] Kermanshah Univ Med Sci, Pharmaceut Sci Res Ctr, Kermanshah, Iran
[4] Inst Adv Studies Basic Sci, Dept Chem, Zanjan 4513766731, Iran
关键词
CuS-Fe3O4/RGO; Ibuprofen; Photocatalysis; Visible light; REMOVAL; NANOCOMPOSITE; CARBON; COMPOSITES; HETEROJUNCTION; NANOPARTICLES; INTERFERENCE; FABRICATION; NANOHYBRID; MECHANISM;
D O I
10.1016/j.inoche.2023.111597
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In this research, the CuS-Fe3O4/RGO catalyst was fabricated for the IBP degradation from aqueous solutions in visible light. The influence of different parameters such as the initial IBP concentration (5-20 mg/L), time (20-120 min), catalyst dosage (0.1-0.4 g/L) and pH (5-9) were considered for the IBP removal by the photo-catalytic process. The results of research indicated that in the removal process of IBP by the CuS-Fe3O4/RGO composite in visible light and in the optimum condition (pH: 7, IBP concentration = 10 mg.L-1, time = 60 min and catalyst dosage = 0.3 g/L) the maximum removals of IBP and total organic carbon (TOC) were 96 % and 50 %, respectively. The byproducts of IBP removal were detected, and the degradation mechanism of IBP was suggested and discussed. After four cycles, the nanocomposite efficiency wasn't decreased significantly. Finally, it can be deduced that the CuS-Fe3O4/RGO nanocomposite has high photocatalytic efficiency for the IBP removal from aqueous solutions.
引用
收藏
页数:11
相关论文
共 66 条
[1]   Graphene Oxide-Doped Polymer Inclusion Membrane for Remediation of Pharmaceutical Contaminant of Emerging Concerns: Ibuprofen [J].
Ahmad, Abdul Latif ;
Ebenezer, Oluwasola Idowu ;
Shoparwe, Noor Fazliani ;
Ismail, Suzylawati .
MEMBRANES, 2022, 12 (01)
[2]   Enhanced efficiency of polyamide membranes by incorporating TiO2-Graphene oxide for water purification [J].
Al-Gamal, Anwar Q. ;
Falath, Wail S. ;
Saleh, Tawfik A. .
JOURNAL OF MOLECULAR LIQUIDS, 2021, 323
[3]   Influence of g-C3N4 and g-C3N4 nanosheets supported CuS coupled system with effect of pH on the catalytic activity of 4-NP reduction using NaBH4 [J].
Ayodhya, Dasari ;
Veerabhadram, Guttena .
FLATCHEM, 2019, 14
[4]   Graphene oxide (rGO)-metal oxide (TiO2/Fe3O4) based nanocomposites for the removal of methylene blue [J].
Banerjee, Soma ;
Benjwal, Poonam ;
Singh, Milan ;
Kar, Kamal K. .
APPLIED SURFACE SCIENCE, 2018, 439 :560-568
[5]   Mesoporous CuS nanospheres decorated rGO aerogel for high photocatalytic activity towards Cr(VI) and organic pollutants [J].
Bano, Zahira ;
Saeed, R. M. Yousaf ;
Zhu, Sidi ;
Xia, MingZhu ;
Mao, Shuai ;
Lei, Wu ;
Wang, Fengyun .
CHEMOSPHERE, 2020, 246
[6]   Synthesis of Fe3O4/Bi2WO6 nanohybrid for the photocatalytic degradation of pharmaceutical ibuprofen under solar light [J].
Bastami, Tahereh Rohani ;
Ahmadpour, Ali ;
Hekmatikar, Fatemeh Ahmadi .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2017, 51 :244-254
[7]   Visible light driven efficient photocatalytic degradation of Congo red dye catalyzed by hierarchical CuS-Bi2CuxW1-xO6-2x nanocomposite system [J].
Bhoi, Yagna Prakash ;
Pradhan, Swaraj Rashmi ;
Behera, Chinmaya ;
Mishra, B. G. .
RSC ADVANCES, 2016, 6 (42) :35589-35601
[8]   Facile synthesis of CuS nanoparticles on two-dimensional nanosheets as efficient artificial nanozyme for detection of Ibuprofen in water [J].
Borthakur, Priyakshree ;
Boruah, Purna K. ;
Das, Manash R. .
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2021, 9 (01)
[9]   Microwave assisted synthesis of CuS-reduced graphene oxide nanocomposite with efficient photocatalytic activity towards azo dye degradation [J].
Borthakur, Priyakshree ;
Boruah, Purna K. ;
Darabdhara, Gitashree ;
Sengupta, Pinaki ;
Das, Manash R. ;
Boronin, Andrei I. ;
Kibis, Lidiya S. ;
Kozlova, Mariia N. ;
Fedorov, Vladimir E. .
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2016, 4 (04) :4600-4611
[10]   Magnetic Fe3O4@V2O5/rGO nanocomposite as a recyclable photocatalyst for dye molecules degradation under direct sunlight irradiation [J].
Boruah, Purna K. ;
Szunerits, Sabine ;
Boukherroub, Rabah ;
Das, Manash R. .
CHEMOSPHERE, 2018, 191 :503-513