Enhanced attenuation of arsenic by Quaternary agricultural soils of Eastern Punjab, India upon anionic clays and gypsum amendment

Agricultural soil of the Sutlej River basin was evaluated for its natural attenuation efficacy for arsenic (As) under the field variables of pH, competitive anions, contact time and varied As contents. The role of layered double hydroxides (HTLDH) and gypsum on uptake efficiency and long-term stability of entrapped As demonstrates rapid As uptake by both geosorbents without mineral structure altering. Arsenic retention by gypsum is poorer than that by HTLDH and greater uptake (similar to 100% within 2 h) was achieved in the co-precipitation process than adsorption on HTLDH. Freundlich isotherm and pseudo-second-order kinetic model fits of the data demonstrate the multilayer rate-limiting sorption process. NO3- and PO43- hardly affected As retention capacity of HTLDH and gypsum with greater retention at pH 6 and high sorbate concentrations. Studied soil shows a strong potential for As (0.68 g kg(-1)) which enhanced upon adding HTLDH, while gypsum lowered As retention efficiency of soil except at pH 6.0. Gypsum exhibited relatively greater desorption than HTLDH where almost no As was desorbed in the latter case within seven days of exposure, but similar to 30% sorbed As gets desorbed from gypsum which was further enhanced by NO3-+PO43- and soil mixing. Identical behaviour was observed from the soil and HTLDH/gypsum mixture at variable ratios as well. This study shows that MgFe-based HTLDH can efficiently retard arsenic mobilization from the soil with competitive anions and wide pH ultimately limiting As bioavailability in the environment and can be successfully used as a potential scavenger for As remediation purposes.