Effect of particle size on electrical impedance, ac conductivity and dielectric properties of ZnSnO3 nanomaterial

被引:1
作者
Khatun, Mamotaj [1 ]
Mukherjee, Sanjoy [1 ]
Mitra, Partha [1 ]
机构
[1] Univ Burdwan, Dept Phys, Burdwan 713104, India
关键词
ZnSnO; 3; nanoparticle; Particle size; Electrical impedance; Ac conductivity; Dielectric property; CHARGE-TRANSPORT; RELAXATION; FILMS;
D O I
10.1016/j.inoche.2023.111443
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In this work, we have reported the electrical impedance, frequency dependent ac conductivity and dielectric properties of zinc stannate (ZnSnO3) nanoparticles synthesized by facile co-precipitation method followed by ball milling for different time span to control particle size. Particle size shows decreasing nature upto a certain span of milling time (2 h) followed by an increase and opposite trend is reflected in band gap. Complex impedance analysis depicts presence of non-Debye type or multiple relaxations and depressed semicircles due to grain and grain boundary. Frequency dependent electrical conductivity analysis shows highest conductivity for two hour milled sample followed by a decrease beyond this. Both real and imaginary component of dielectric constant is also maximum for two hour milled sample.
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页数:6
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