Influence of phthalocyanine nanowire dye on the performance of titanium dioxide-metal organic framework nanocomposite for dye-sensitized solar cells

被引:8
|
作者
Ramaripa, Phuti S. [1 ]
Modibane, Kwena D. [1 ]
Makgopa, Katlego [2 ]
Seerane, Ostar A. [2 ]
Maubane-Nkadimeng, Manoko S. [3 ,4 ,5 ]
Makhado, Edwin [1 ]
Pandey, Sadanand [6 ]
机构
[1] Univ Limpopo Turfloop, Sch Phys & Mineral Sci, Dept Chem, Nanotechnol Res Grp, ZA-0727 Polokwane, South Africa
[2] Tshwane Univ Technol, Fac Sci, Dept Chem, Arcadia Campus, ZA-0001 Pretoria, South Africa
[3] Univ Witwatersrand, DSI NRF Ctr excellence Strong Mat, Private Bag X3, Wits, ZA-2050 Johannesburg, South Africa
[4] Univ Witwatersrand, Mol Sci Inst, Sch Chem, Private Bag X3, Wits, ZA-2050 Johannesburg, South Africa
[5] Univ Witwatersrand, Microscopy & Microanal Unit, Private Bag 3, ZA-2050 Johannesburg, South Africa
[6] Yeungnam Univ, Coll Nat Sci, Dept Chem, 280 Daehak Ro, Gyeongbuk 38541, Gyeongsan, South Korea
来源
CHEMICAL ENGINEERING JOURNAL ADVANCES | 2023年 / 14卷
基金
新加坡国家研究基金会;
关键词
Phthalocyanine nanowire; Titanium dioxide; Metal-organic framework; Nanocomposite; Dye-sensitized solar cells; PHOTOCATALYTIC ACTIVITY; RHODAMINE-B; TIO2; FILM; EFFICIENCY; ELECTRODE; COMPOSITE; PHOTODEGRADATION; ELECTROCATALYST; DEGRADATION; FABRICATION;
D O I
10.1016/j.ceja.2023.100485
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In clean energy, dye-sensitized solar cells (DSSCs) have become a key tool for the photovoltaic effect. Copper phthalocyanine nanowire (CuPcNW) dyes can be used in DSSCs to generate low-cost devices, light-harvesting, fast electron transfer materials, and prevent recombination processes, as well as improve conductivity. This study investigates the effect of CuPcNW dye on TiO2, MOF, and TiO2-MOF in photovoltaic performance. Electrochemical characterizations such as cyclic voltammetry and electrochemical impedance spectroscopy (EIS) have also revealed the half-wave peak potentials of the ternary nanocomposite with values of 0.44 and 0.35 V for the oxidation and reduction reversible reactions. The EIS behavior revealed the improved conductivity of the nanocomposite with a value of 244 & mu;S/cm. It was seen that the TiO2-MOF/CuPcNW nanocomposite achieved a maximum power conversion efficiency of 6.467 % owing to the presence of CuPcNW, which improved the photocurrent density, faster electron transport, and reduced charge recombination in the nanocomposite.
引用
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页数:12
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