Playing with the cavity size of exTTF-based self-assembled cages

被引：2

作者：

Dekhtiarenko, Maksym ^{[1
,2
]}

Szaloki, Gyoergy ^{[1
]}

Croue, Vincent ^{[1
]}

Bou Zeid, Jennifer ^{[1
]}

Canevet, David ^{[1
]}

Allain, Magali ^{[1
]}

Carre, Vincent ^{[3
]}

Aubriet, Frederic ^{[3
]}

Voitenko, Zoia ^{[2
]}

Salle, Marc ^{[1
]}

Goeb, Sebastien ^{[1
]}

机构：

[1] Univ Angers, CNRS, MOLTECH Anjou, F-49000 Angers, France

[2] Taras Shevchenko Natl Univ Kyiv, 64-13 Volodymyrska St, UA-01033 Kiev, Ukraine

[3] Univ Lorraine, LCP A2MC, F-57000 Metz, France

来源：

ORGANIC CHEMISTRY FRONTIERS | 2023年 / 10卷 / 07期

关键词：

COORDINATION CAGES; GUEST; COMPLEXES; DESIGN; HOST; METALLOMACROCYCLES; METALLACYCLES; CONSTRUCTION; PRINCIPLES; SEPARATION;

D O I：

10.1039/d3qo00214d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

M4L2 metalla-cages bearing large electron-rich ovoid cavities constructed through coordination-driven self-assembly from square planar palladium complexes and extended tetrathiafulvalene (exTTF)-based ligands are depicted. Their binding properties for polyaromatic hydrocarbons (PAHs) or zinc tetraphenylporphyrin have been evaluated and compared with previously described smaller cage analogues, showing a high size selectivity.

引用

页码：1803 / 1810

页数：8

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