Seasonal variations and water chemical control mechanism of water quality in a suburban river near a coal city: a case study in the Xinbian River of Suzhou City, Anhui Province, China

To study the seasonal change rules of water quality indicators and water chemical control mechanisms in the nearby city river Xinbian River, in Suzhou City, Anhui Province, China, nine points were selected and periodically sampled for 12 months. Totally 108 water samples were collected, and basic physical-chemical indicators and routine ions (e.g., Ca2+, Mg2+, Na+, K+, SO42-, Cl-, F-, NO3-, CO32-, and HCO3-) were measured. Piper diagram, Gibbs diagram, and ion ratio method were used. The result shows that the seasonal and upstream-to-downstream variations in pH were less varied, whereas the fluctuation in dissolved oxygen was large. Four ions, namely, SO42-, F-, Cl-, and Na+ generally first decreased overall and then changed from spring to winter. The maximum contents of SO42- (406.03 mg/L), Cl- (250.22 mg/L), and Na+ (269.99 mg/L) in single water samples appeared at the S9 sampling point (Suzhou control gate) in March 2020. The dominant hydrochemical types in summer were Na-Ca-HCO3 and Na-Mg-SO4, while Na-Mg-SO4 and Na-Mg-HCO3 were the main hydrochemical types in the other seasons. The control factors of water chemical composition vary according to the season. However, rock weathering (e.g., silicate dissolution) is the dominant control factor of water chemistry in the studied river section.