Metastable to stable phase transformation in atmospheric plasma sprayed Yb-silicate coating during post-heat treatment

被引：17

作者：

Bakan, Emine ^{[1
]}

Sohn, Yoo Jung ^{[1
]}

Vassen, Robert ^{[1
]}

机构：

[1] Forschungszentrum Julich, Inst Energy & Climate Res Mat Synth & Proc IEK 1, D-52425 Julich, Germany

来源：

SCRIPTA MATERIALIA | 2023年 / 225卷

关键词：

Environmental barrier coating; Plasma spray; Phase transformation; Crystallization; Crack healing; ENVIRONMENTAL BARRIER COATINGS; SIO2 SCALE VOLATILITY; WATER-VAPOR; COMBUSTION CONDITIONS; OXIDATION; CRYSTALLIZATION; BEHAVIOR;

D O I：

10.1016/j.scriptamat.2022.115169

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Yb-silicate is used as volatilization barrier material in environmental barrier coating applications. In this study, metastable to stable phase transformation in highly amorphous atmospheric plasma sprayed Yb-silicate coating was investigated during post-heat treatment. High-temperature X-ray diffraction (HT-XRD) was used to analyze the phase composition of the coating at elevated temperatures. Three metastable phases (Yb2Si2O7 (P-1), Yb2SiO5 (P21/c), Yb4.67Si3O13 (P63/m)) and two stable phases (Yb2Si2O7 (C2/m), Yb2SiO5 (I2/a)) preferentially crystallized from the amorphous coating starting at 1000 degrees C. Metastable phases transformed into stable Yb2Si2O7 and Yb2SiO5 at higher temperatures. HT-XRD data were used to estimate the volume expansion in the coating due to the phase transformation and the results were compared to the dilatometry measurements. The estimated expansion from HT-XRD data was larger than the measured expansion in dilatometry. Microstructural investigation revealed crack healing in the coating during the measurements which was associated with the lower expansion measured in dilatometry.

引用

页数：5

共 31 条

[1] Observation of Gravitational Waves from a Binary Black Hole Merger [J].

Abbott, B. P. ;

Abbott, R. ;

Abbott, T. D. ;

Abernathy, M. R. ;

Acernese, F. ;

Ackley, K. ;

Adams, C. ;

Adams, T. ;

Addesso, P. ;

Adhikari, R. X. ;

Adya, V. B. ;

Affeldt, C. ;

Agathos, M. ;

Agatsuma, K. ;

Aggarwal, N. ;

Aguiar, O. D. ;

Aiello, L. ;

Ain, A. ;

Ajith, P. ;

Allen, B. ;

Allocca, A. ;

Altin, P. A. ;

Anderson, S. B. ;

Anderson, W. G. ;

Arai, K. ;

Arain, M. A. ;

Araya, M. C. ;

Arceneaux, C. C. ;

Areeda, J. S. ;

Arnaud, N. ;

Arun, K. G. ;

Ascenzi, S. ;

Ashton, G. ;

Ast, M. ;

Aston, S. M. ;

Astone, P. ;

Aufmuth, P. ;

Aulbert, C. ;

Babak, S. ;

Bacon, P. ;

Bader, M. K. M. ;

Baker, P. T. ;

Baldaccini, F. ;

Ballardin, G. ;

Ballmer, S. W. ;

Barayoga, J. C. ;

Barclay, S. E. ;

Barish, B. C. ;

Barker, D. ;

Barone, F. .

PHYSICAL REVIEW LETTERS, 2016, 116 (06)

[2] Effect of processing on high-velocity water vapor recession behavior of Yb-silicate environmental barrier coatings [J].

Bakan, Emine ;

Sohn, Yoo Jung ;

Kunz, Willy ;

Klemm, Hagen ;

Vassen, Robert .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2019, 39 (04) :1507-1513

[3] Yb2Si2O7 Environmental Barrier Coatings Deposited by Various Thermal Spray Techniques: A Preliminary Comparative Study [J].

Bakan, Emine ;

Marcano, Diana ;

Zhou, Dapeng ;

Sohn, Yoo Jung ;

Mauer, Georg ;

Vassen, Robert .

JOURNAL OF THERMAL SPRAY TECHNOLOGY, 2017, 26 (06) :1011-1024

[4]

Chamberlain A., 2012, P ULTRA HIGH TEMPERA

[5] GENERAL RELATIONSHIP FOR THERMAL OXIDATION OF SILICON [J].

DEAL, BE ;

GROVE, AS .

JOURNAL OF APPLIED PHYSICS, 1965, 36 (12) :3770-&

[6] Surface crystallization and texture in cordierite glasses [J].

Diaz-Mora, N ;

Zanotto, ED ;

Hergt, R ;

Müller, R .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2000, 273 (1-3) :81-93

[7]

Eaton H.E., 2000, ASME TURBO EXPO 2000

[8] RARE-EARTH SILICATES WITH APATITE STRUCTURE [J].

FELSCHE, J .

JOURNAL OF SOLID STATE CHEMISTRY, 1972, 5 (02) :266-&

[9] Corrosion of selected ceramic materials in hot gas environment [J].

Fritsch, Marco ;

Klemm, Hagen ;

Herrmann, Matthias ;

Schenk, Bjoern .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2006, 26 (16) :3557-3565

[10] Phase and microstructure evolution in plasma sprayed Yb2Si2O7 coatings [J].

Garcia, E. ;

Lee, H. ;

Sampath, S. .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2019, 39 (04) :1477-1486

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