Comparative study of NH3 and H2 impacts on combustion and emission characteristics of n-Hexadecane under different flame conditions

The addition of renewable fuel to hydrocarbon fuel mitigated the carbon monoxide, carbon dioxide and soot particle emissions of internal combustion engines. A comparative study of the ammonia and hydrogen effect on combustion and emission characteristics of n-hexadecane flames was executed at various flame conditions. The results showed that alternative fuels had a stronger impact on peak temperature at diffusion flame conditions rather than at premixed flame conditions. The premixed flame released carbon monoxide emission lower than the diffusion flames with/without additional fuels. The carbon monoxide emissions decreased highly with ammonia enrichment instead of hydrogen. At premixed and coflow diffusion flame conditions, the ammonia highly reduced carbon dioxide emission compared to hydrogen. Hydrogen addition reduced the nitrogen oxide emission, whereas it was increased by ammonia. The soot particle number density was reduced highly by hydrogen addition instead of ammonia at the premixed flow flame and diffusion coflow flame conditions. The impact of hydrogen on the reduction of soot mass concentration emissions was greater than that of ammonia at all combustion conditions. It is suggested that H2 > 70% should be mixed in n-hexadecane fuel because a higher burning velocity can be achieved with a higher emission reduction. A reduction in the emission of carbon-related species can be realized with a small reduction in burning velocity at NH3 < 70%.(c) 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.