Pt1/4Pd separation modified Ti3C2TX MXene for hydrogen detection at room temperature

被引：9
作者：
Wang, Lei [1 ,2 ]
Xiao, Zhikun [1 ,2 ]
Yao, Xinqi [1 ,2 ]
Yu, Xinhai [1 ,2 ]
Tu, Shan-Tung [1 ,2 ]
Chen, Shijian [3 ]
机构：
[1] East China Univ Sci & Technol, MOE Key Lab Pressure Syst & Safety, Shanghai 200237, Peoples R China
[2] East China Univ Sci & Technol, Sch Mech & Power Engn, Shanghai 200237, Peoples R China
[3] SUFA Technol Ind Co Ltd, CNNC, Suzhou 215001, Peoples R China
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2023年 / 48卷 / 77期
关键词：
Hydrogen sensor; Bimetallic; MXene; Room temperature; Fast response; CARBON NANOTUBE; DETECTION RANGE; PD; SENSOR; PALLADIUM; TIO2; PERFORMANCE; OXIDATION; NANOWIRES; GRAPHENE;
D O I：
10.1016/j.ijhydene.2023.04.202
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Hydrogen sensing with a fast response at room temperature is still a challenge. In this study, a novel Pt=Pd/Ti3C2TX hydrogen sensor was prepared by a straightforward hydro thermal chemical reduction method. The Pt=Pd/Ti3C2TX was characterized by X-ray diffraction, transmission electron microscope, and X-ray photoelectron spectroscopy. The experimental results showed that the response of the Pt=Pd/Ti3C2TX sensor was 24.6% and the response/recovery time was 6/8 s in the case of 200 ppm hydrogen at room temperature. The Pt=Pd/Ti3C2TX sensor could detect the hydrogen concentration as low as 1 ppm. Besides, the Pt=Pd/Ti3C2TX sensor exhibited good linearity, long-term stability, good repeatability, and high selectivity. The Pt=Pd/Ti3C2TX sensor has great potential in the field of hydrogen energy.(c) 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：30205 / 30217
页数：13
相关论文
共 79 条
[1]   The role of palladium in a hydrogen economy [J].
Adams, Brian D. ;
Chen, Aicheng .
MATERIALS TODAY, 2011, 14 (06) :282-289
[2]   Low-Temperature Hydrogen Sensor: Enhanced Performance Enabled through Photoactive Pd-Decorated TiO2 Colloidal Crystals [J].
Alenezy, Ebtsam K. ;
Sabri, Ylias M. ;
Kandjani, Ahmad E. ;
Korcoban, Dilek ;
Rashid, Syed Sulthan Alaudeen Abdul Haroon ;
Ippolito, Samuel J. ;
Bhargava, Suresh K. .
ACS SENSORS, 2020, 5 (12) :3902-3914
[3]   Guidelines for Synthesis and Processing of Two-Dimensional Titanium Carbide (Ti3C2TX MXene) [J].
Alhabeb, Mohamed ;
Maleski, Kathleen ;
Anasori, Babak ;
Lelyukh, Pavel ;
Clark, Leah ;
Sin, Saleesha ;
Gogotsi, Yury .
CHEMISTRY OF MATERIALS, 2017, 29 (18) :7633-7644
[4]   Intermetallic Pd-In/HOPG model catalysts: Reversible tuning the surface structure by O2-induced segregation [J].
Bukhtiyarov, A. V. ;
Panafidin, M. A. ;
Chetyrin, I. A. ;
Prosvirin, I. P. ;
Mashkovsky, I. S. ;
Smirnova, N. S. ;
Markov, P. V. ;
Zubavichus, Y. V. ;
Stakheev, A. Yu. ;
Bukhtiyarov, V. I. .
APPLIED SURFACE SCIENCE, 2020, 525
[5]   Hydrogen gas sensing methods, materials, and approach to achieve parts per billion level detection: A review [J].
Chauhan, Pankaj Singh ;
Bhattacharya, Shantanu .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (47) :26076-26099
[6]   Hollow PtCu nanoparticles encapsulated into a carbon shell via mild annealing of Cu metal-organic frameworks [J].
Chen, Guanjun ;
Shan, Huaqiang ;
Li, Yan ;
Bao, Hongwei ;
Hu, Tingwei ;
Zhang, Long ;
Liu, Shuai ;
Ma, Fei .
JOURNAL OF MATERIALS CHEMISTRY A, 2020, 8 (20) :10337-10345
[7]   Efficient Z-Scheme heterostructure based on TiO2/Ti3C2Tx/Cu2O to boost photoelectrochemical response for ultrasensitive biosensing [J].
Chen, Guojuan ;
Wang, Hengjia ;
Wei, Xiaoqian ;
Wu, Yu ;
Gu, Wenling ;
Hu, Liuyong ;
Xu, Dacheng ;
Zhu, Chengzhou .
SENSORS AND ACTUATORS B-CHEMICAL, 2020, 312
[8]   Design of efficient noble metal single-atom and cluster catalysts toward low-temperature preferential oxidation of CO in H2 [J].
Chen, Yang ;
Lin, Jian .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2023, 48 (64) :24788-24808
[9]   Ultrasmall Grained Pd Nanopattern H2 Sensor [J].
Cho, Soo-Yeon ;
Ahn, Hyunah ;
Park, Kangho ;
Choi, Junghoon ;
Kang, Hohyung ;
Jung, Hee-Tae .
ACS SENSORS, 2018, 3 (09) :1876-1883
[10]   Fast responding and highly reversible gasochromic H2 sensor using Pd-decorated amorphous WO3 thin films [J].
Cho, Sung Hwan ;
Suh, Jun Min ;
Jeong, Beomgyun ;
Lee, Tae Hyung ;
Choi, Kyoung Soon ;
Eom, Tae Hoon ;
Kim, Taehoon ;
Jang, Ho Won .
CHEMICAL ENGINEERING JOURNAL, 2022, 446
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