Transmission Electron Microscopy Characterizations of Local Amorphization of Single Crystal Silicon by Nanosecond Pulsed Laser Direct Writing

The concept for fabrication of waveguides by an in-volume laser direct writing in single-crystal silicon is explored using a nanosecond pulse laser. The key innovation of this technology relies on the generation of amorphous silicon, which has a higher refractive index than that of crystalline silicon. Herein, transmission electron microscopy (TEM) together with selected area electron diffraction (SAED) and high-resolution TEM (HRTEM) characterizations are used to better understand the microstructural evolutions. TEM images reveal the core-shell structures, while SAED patterns and HRTEM directly observe the presence of amorphous silicon in the core surrounded by a crystalline silicon shell. With a lower laser scanning speed, a higher density of defects yet less amorphous silicon is formed by laser direct writing. The concept for fabrication of waveguides by an in-volume laser direct writing in single-crystal silicon is explored using a nanosecond pulse laser. The transmission electron microscopy (TEM) images reveal core-shell structures, while selected area electron diffraction patterns and high-resolution TEM observe the presence of amorphous silicon with a higher refractive index in the core surrounded by a crystalline silicon shell.image (c) 2023 WILEY-VCH GmbH