Sticky Multicolor Mechanochromic Labels

被引:9
作者
de Castro, Lucas D. C. [1 ,2 ]
Engels, Tom A. P. [3 ]
Oliveira Jr, Osvaldo N. [1 ]
Schenning, Albert P. H. J. [2 ,4 ]
机构
[1] Univ Sao Paulo, Sao Carlos Inst Phys, BR-13566590 Sao Carlos, SP, Brazil
[2] Eindhoven Univ Technol, Dept Chem Engn & Chem, Lab Stimuli Respons Funct Mat & Devices SFD, NL-5612 MB Eindhoven, Netherlands
[3] Eindhoven Univ Technol, Dept Mech Engn, Proc & Performance Mat, NL-5600 MB Eindhoven, Netherlands
[4] Eindhoven Univ Technol, Inst Complex Mol Syst, NL-5612 MB Eindhoven, Netherlands
关键词
mechanochromic devices; cholesteric liquid crystal elastomers; stickers; labels; wearable devices; ELASTOMERS;
D O I
10.1021/acsami.3c19420
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Sticky-colored labels are an efficient way to communicate visual information. However, most labels are static. Here, we propose a new category of dynamic sticky labels that change structural colors when stretched. The sticky mechanochromic labels can be pasted on flexible surfaces such as fabric and rubber or even on brittle materials. To enhance their applicability, we demonstrate a simple method for imprinting structural color patterns that are either always visible or reversibly revealed or concealed upon mechanical deformation. The mechanochromic patterns are imprinted with a photomask during the ultraviolet (UV) cross-linking of acrylate-terminated cholesteric liquid crystal oligomers in a single step at room temperature. The photomask locally controls the cross-linking degree and volumetric response of the cholesteric liquid crystal elastomers (CLCEs). A nonuniform thickness change induced by the Poisson's ratio contrast between the pattern and the surrounding background might lead to a color-separation effect. Our sticky multicolor mechanochromic labels may be utilized in stress-strain sensing, building environments, smart clothing, security labels, and decoration.
引用
收藏
页码:14144 / 14151
页数:8
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