Complexes of Cu(II), Co(II), and Zn(II) Terephthalates with Hydroxyalkylamines

被引:6
|
作者
Zav'yalova, D. A. [1 ,2 ]
Kondratenko, Yu. A. [1 ]
Zolotarev, A. A. [3 ]
Ugolkov, V. L. [1 ]
Kochina, T. A. [1 ]
机构
[1] Russian Acad Sci, Grebenshchikov Inst Silicate Chem, St Petersburg, Russia
[2] Tech Univ, St Petersburg State Technol Inst, St Petersburg, Russia
[3] St Petersburg State Univ, Inst Earth Sci, St Petersburg, Russia
关键词
metal-organic frameworks; coordination polymers; hydrometallatranes; hydroxyalkylamines; terephthalic acid; crystal structure; TRIETHANOLAMINE COMPLEXES; COPPER(II) COMPLEXES; CRYSTAL-STRUCTURE; SUPRAMOLECULAR ARCHITECTURES; PEROXIDATIVE OXIDATION; ACID; COBALT(II); LUMINESCENCE; BEHAVIOR;
D O I
10.1134/S1070328423600389
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
reactions of Cu(II), Co(II), and Zn(II) terephthalates with hydroxyalkylamines (tris(2hydroxyethyl)amine, bis(2-hydroxyethyl)amine, tris(hydroxymethyl)aminomethane, and bis(2hydroxyethyl)aminotris(hydroxymethyl)methane) are studied for the first time. The structures and properties of the synthesized complexes are studied by IR spectroscopy, electronic absorption spectroscopy, mass spectrometry, and elemental and thermal analyses. The structure of the binuclear heteroligand [Cu-2(TEA)(2)(Tph)](n).H2O complex is studied by single-crystal X-ray diffraction (XRD) (CIF file CCDC no. 2224437).
引用
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页码:486 / 495
页数:10
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