Upcycling of Agricultural Waste Stream to High-Molecular-Weight Bio-based Poly(ethylene 2,5-furanoate)

被引：2

作者：

Niskanen, Jukka ^{[1
]}

Mahlberg, Riitta ^{[1
]}

van Strien, Nicolaas ^{[1
]}

Rautiainen, Sari ^{[1
]}

Kivilahti, Essi ^{[1
]}

Koivuranta, Kari ^{[1
]}

Anghelescu-Hakala, Adina ^{[1
]}

机构：

[1] VTT Tech Res Ctr Finland Ltd, FI-02044 Espoo, Finland

来源：

CHEMSUSCHEM | 2024年 / 17卷 / 09期

关键词：

poly(ethylene 2,5-furanoate); bio-based; polycondensation; enzymatic degradation; furan dicarboxylic acid; DIETHYLENE GLYCOL FORMATION; SOLID-STATE POLYMERIZATION; 2,5-FURANDICARBOXYLIC ACID; GALACTARIC ACID; POLYESTERS; POLY(ETHYLENE-TEREPHTHALATE); KINETICS; ESTERIFICATION; TEREPHTHALATE; DEGRADATION;

D O I：

10.1002/cssc.202301551

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Orange peel and sugar beet pulp contain large quantities of pectin, which can be turned via galactaric acid into furan dicarboxylic acid (FDCA) and its esters. In this work, we show the polymerisation of these FDCA esters into high-molecular-weight, 70-100 kg/mol, poly(ethylene 2,5-furanoate) (PEF). PEF is an emerging bio-based alternative for poly(ethylene terephthalate) (PET), widely used in for example packaging applications. Closing the loop, we also demonstrated and confirmed that PEF can be hydrolysed by enzymes, which are known to hydrolyse PET, back into FDCA for convenient recycling and recovery of monomers. Orange peel and sugar beet pulp contain pectin, which can be turned into furan dicarboxylic acid (FDCA) and its esters. In this work, we show the polymerisation of these esters into high-molecular-weight poly(ethylene 2,5-furanoate) (PEF). PEF is an emerging bio-based alternative for poly(ethylene terephthalate) (PET). Closing the loop, we also demonstrated and confirmed that PEF can be hydrolysed by enzymes. image

引用

页数：8

共 58 条

[1] Inside PEF: Chain Conformation and Dynamics in Crystalline and Amorphous Domains [J].

Araujo, Catarina F. ;

Nolasco, Mariela M. ;

Ribeiro-Claro, Paulo J. A. ;

Rudic, Svemir ;

Silvestre, Armando J. D. ;

Vaz, Pedro D. ;

Sousa, Andreia F. .

MACROMOLECULES, 2018, 51 (09) :3515-3526

[2]

Asikainen M., 2016, [No title captured], Patent No. [EP3283471, 3283471]

[3] Insights into the Synthesis of Poly(ethylene 2,5-Furandicarboxylate) from 2,5-Furandicarboxylic Acid: Steps toward Environmental and Food Safety Excellence in Packaging Applications [J].

Banella, Maria Barbara ;

Bonucci, Jacopo ;

Vannini, Micaela ;

Marchese, Paola ;

Lorenzetti, Cesare ;

Celli, Annamaria .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2019, 58 (21) :8955-8962

[4] Isosorbide and 2,5-Furandicarboxylic Acid Based (Co)Polyesters: Synthesis, Characterization, and Environmental Degradation [J].

Bouyahya, Chaima ;

Patricio, Rafael ;

Paco, Ana ;

Lima, Mafalda S. ;

Fonseca, Ana C. ;

Rocha-Santos, Teresa ;

Majdoub, Mustapha ;

Silvestre, Armando J. D. ;

Sousa, Andreia F. .

POLYMERS, 2022, 14 (18)

[5] Technology development for the production of biobased products from biorefinery carbohydrates-the US Department of Energy's "Top 10" revisited [J].

Bozell, Joseph J. ;

Petersen, Gene R. .

GREEN CHEMISTRY, 2010, 12 (04) :539-554

[6] Oxygen sorption and transport in amorphous poly(ethylene furanoate) [J].

Burgess, Steven K. ;

Karvan, Oguz ;

Johnson, J. R. ;

Kriegel, Robert M. ;

Koros, William J. .

POLYMER, 2014, 55 (18) :4748-4756

[7] Chain Mobility, Thermal, and Mechanical Properties of Poly(ethylene furanoate) Compared to Poly(ethylene terephthalate) [J].

Burgess, Steven K. ;

Leisen, Johannes E. ;

Kraftschik, Brian E. ;

Mubarak, Christopher R. ;

Kriegel, Robert M. ;

Koros, William J. .

MACROMOLECULES, 2014, 47 (04) :1383-1391

[8]

Chen JW, 1999, J POLYM SCI POL CHEM, V37, P1797, DOI 10.1002/(SICI)1099-0518(19990615)37:12<1797::AID-POLA9>3.0.CO

[9]

2-3

[10]

Chen JW, 1998, J POLYM SCI POL CHEM, V36, P3073, DOI 10.1002/(SICI)1099-0518(199812)36:17<3073::AID-POLA8>3.0.CO

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