Synthesis and characterization of amide-Functionalized analogues of glycine-betaine based ionic liquids and an exemplified use for the separation of copper(II) and cobalt(II)

被引：0
|
作者：
Diabate, Pape Diaba [1 ]
Boulafrouh, Lamia [1 ]
Boudesocque, Stephanie [1 ]
Dupont, Laurent [1 ]
Mohamadou, Aminou [1 ,2 ]
机构：
[1] Univ Reims, Inst Chim Mol Reims ICMR, UMR CNRS 7312, Moulin Housse, Reims, France
[2] Univ Reims, Inst Chim Mol Reims ICMR, UMR CNRS 7312, BP 1039,Moulin Housse, F-51687 Reims 2, France
来源：
SEPARATION SCIENCE AND TECHNOLOGY | 2023年 / 58卷 / 09期
关键词：
Ionic liquids; glycine-betaine; liquid-liquid extraction; copper; cobalt; PHYSICOCHEMICAL PROPERTIES; EXTRACTION; ANION; SACCHARINATE; TRANSITION; AMMONIUM; SOLVENTS; GREENER;
D O I：
10.1080/01496395.2023.2202808
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Novel series of amide functionalized analogues of glycine-betaine-based ionic liquids (AGB-ILs), namely, [N,N,N-tri(n-butyl)(2-aminoalkyl-2-oxoethyl)]ammonium (alkyl = n-butyl, and n-octyl) associated with tetrafluoroborate (BF4-), hexafluorophosphate (PF6-), bis(trifluorosulfonyl)imide (Tf2N-), dicyanamide (Dca(-)), 4-chlorosalicylate (ClSal(-)) and saccharinate (Sac(-)) anions have been synthesized and fully characterized by spectroscopic methods (IR, H-1 and C-13 NMR) and elemental analysis. The alkyl chain length of the organic cation and the chemical nature of inorganic or organic anion on physicochemical properties such as melting point, glass transition and decomposition temperatures, and viscosity have been described. To determine the sensitivity of Dca ligand to pH, the effect of the pH on the extraction properties of aqueous Cu2+ and Co2+ ions has been investigated in the pH range 1 to 5.
引用
收藏
页码：1689 / 1702
页数：14
相关论文
共 34 条
  • [21] Synthesis, characterization, and anticancer activity of chitosan functionalized isatin based thiosemicarbazones, and their copper (II) complexes
    Adhikari, Hari Sharan
    Garai, Aditya
    Yadav, Paras Nath
    CARBOHYDRATE RESEARCH, 2023, 526
  • [22] Cobalt(II), nickel(II), copper(II) and zinc(II) complexes of thiadiazole based Schiffbase ligands: Synthesis, structural characterization, DFT, antidiabetic and molecular docking studies
    Deswal, Yogesh
    Asija, Sonika
    Dubey, Amit
    Deswal, Laxmi
    Kumar, Deepak
    Jindal, Deepak Kumar
    Devi, Jai
    JOURNAL OF MOLECULAR STRUCTURE, 2022, 1253
  • [23] Benzo[h]quinoline based Macrocyclic Copper(II), Cobalt(II) Complexes: Synthesis, Characterization and Light induced DNA Cleavage Studies
    Naik, H. R. Prakash
    Naik, H. S. Bhojya
    Lamani, D. S.
    Aravinda, T.
    Kumar, B. Vijaya
    Kumar, B. Vinay
    Yogesh, M.
    Sharath, N.
    Kumar, P. N. Prashanth
    JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2009, 46 (08): : 790 - 795
  • [24] Synthesis, characterization and use of imidazole and methyl-pyrazole based pyridine ligands as extractants for nickel(II) and copper(II)
    Pearce, Brendan H.
    Ogutu, Hezron F. O.
    Saban, Waheed
    Luckay, Robert C.
    INORGANICA CHIMICA ACTA, 2019, 490 : 57 - 67
  • [25] Synthesis and characterization of N3Py2 ligand-based cobalt(II), nickel (II) and copper(II) catalysts for efficient conversion of hydrocarbons to alcohols
    Narulkar, Dattaprasad D.
    Srivastava, Anant Kumar
    Butcher, Raymond J.
    Ansy, Kanakappan M.
    Dhuri, Sunder N.
    INORGANICA CHIMICA ACTA, 2017, 467 : 405 - 414
  • [26] Synthesis, characterization and structures of binuclear copper(II) and polynuclear cobalt(II), nickel(II) and cadmium(II) complexes involving N4-donor pyrazolyl based ligand and dicyanamide as bridging ligand
    Munshi, Sadeka J.
    Sadhu, Mehul H.
    Kundu, Suman
    Savani, Chirag
    Kumar, Sujit B.
    JOURNAL OF MOLECULAR STRUCTURE, 2020, 1209
  • [27] Synthesis, Structural Characterization, in Vitro Biological Activity, and Computational Quantum Chemical Studies of New Cobalt (II), Nickel (II), and Copper (II) Complexes Based on an Azo-Azomethine Ligand
    Naderi, Fatemeh
    Orojloo, Masoumeh
    Kamali, Shirin
    Jannesar, Ramin
    Amani, Saeid
    POLYCYCLIC AROMATIC COMPOUNDS, 2023, 43 (03) : 2582 - 2598
  • [28] Copper(II) and Cobalt(II) Complexes Based on Abietate Ligands from Pinus Resin: Synthesis, Characterization and Their Antibacterial and Antiviral Activity against SARS-CoV-2
    Correa, Jamille de S.
    Primo, Julia de O.
    Balaba, Nayara
    Pratsch, Christoph
    Werner, Stephan
    Toma, Henrique E.
    Anaissi, Fauze J.
    Wattiez, Ruddy
    Zanette, Cristina M.
    Onderwater, Rob C. A.
    Bittencourt, Carla
    NANOMATERIALS, 2023, 13 (07)
  • [29] Synthesis, characterization and structures of copper(II) complexes with amide-based ligands: Unusual formation of a linear trimer and a zig-zag chain and their contrast magnetic behaviour
    Singh, Jyoti
    Hundal, Geeta
    Corbella, Montserrat
    Gupta, Rajeev
    POLYHEDRON, 2007, 26 (14) : 3893 - 3903
  • [30] An Oxalate-Bridged Copper(II) Dimer and a Mononuclear Cobalt(III) Azide Complex Containing N-Nitrile-Functionalized 1,4,7-Triazacyclononane Terminals: Synthesis, Crystal Structure, and Magnetic Characterization
    Zhang, Zhong
    Shao, Da-Lin
    Geng, Zhi-Rong
    Wang, Zhi-Lin
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2012, 638 (05): : 821 - 825
1234