Synthesis and characterization of amide-Functionalized analogues of glycine-betaine based ionic liquids and an exemplified use for the separation of copper(II) and cobalt(II)

被引：0
|
作者：
Diabate, Pape Diaba [1 ]
Boulafrouh, Lamia [1 ]
Boudesocque, Stephanie [1 ]
Dupont, Laurent [1 ]
Mohamadou, Aminou [1 ,2 ]
机构：
[1] Univ Reims, Inst Chim Mol Reims ICMR, UMR CNRS 7312, Moulin Housse, Reims, France
[2] Univ Reims, Inst Chim Mol Reims ICMR, UMR CNRS 7312, BP 1039,Moulin Housse, F-51687 Reims 2, France
来源：
SEPARATION SCIENCE AND TECHNOLOGY | 2023年 / 58卷 / 09期
关键词：
Ionic liquids; glycine-betaine; liquid-liquid extraction; copper; cobalt; PHYSICOCHEMICAL PROPERTIES; EXTRACTION; ANION; SACCHARINATE; TRANSITION; AMMONIUM; SOLVENTS; GREENER;
D O I：
10.1080/01496395.2023.2202808
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Novel series of amide functionalized analogues of glycine-betaine-based ionic liquids (AGB-ILs), namely, [N,N,N-tri(n-butyl)(2-aminoalkyl-2-oxoethyl)]ammonium (alkyl = n-butyl, and n-octyl) associated with tetrafluoroborate (BF4-), hexafluorophosphate (PF6-), bis(trifluorosulfonyl)imide (Tf2N-), dicyanamide (Dca(-)), 4-chlorosalicylate (ClSal(-)) and saccharinate (Sac(-)) anions have been synthesized and fully characterized by spectroscopic methods (IR, H-1 and C-13 NMR) and elemental analysis. The alkyl chain length of the organic cation and the chemical nature of inorganic or organic anion on physicochemical properties such as melting point, glass transition and decomposition temperatures, and viscosity have been described. To determine the sensitivity of Dca ligand to pH, the effect of the pH on the extraction properties of aqueous Cu2+ and Co2+ ions has been investigated in the pH range 1 to 5.
引用
收藏
页码：1689 / 1702
页数：14
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