Hydrogen release from hydrolysis of NaBH4-NH3BH3 composite promoted by CoCl2•6H2O

被引:1
作者
Yang, M. [1 ]
Wu, Y. C. [1 ]
Liu, Y. H. [1 ]
Chen, J. Q. [1 ]
Wu, C. L. [2 ]
Feng, W. [1 ,3 ,4 ]
Cai, W. T. [5 ,6 ]
Wang, X. L. [1 ,3 ,4 ]
机构
[1] Chengdu Univ, Sch Mech Engn, Chengdu 610106, Peoples R China
[2] Sichuan Univ, Engn Res Ctr Alternat Energy Mat & Devices, Minist Educ, Chengdu 610065, Peoples R China
[3] Chengdu Univ, Sichuan Prov Engn Technol Res Ctr Powder Met, Chengdu 610106, Peoples R China
[4] Chengdu Univ, Inst Adv Study, Chengdu 610106, Peoples R China
[5] Guangdong Univ Technol, Sch Mat & Energy, Guangzhou 510006, Peoples R China
[6] South China Univ Technol, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510006, Peoples R China
基金
中国国家自然科学基金;
关键词
Hydrolysis; Hydrogen release; NaBH4; NH3BH3; CoCl2; COBALT-BASED CATALYSTS; SODIUM-BOROHYDRIDE; AMMONIA-BORANE; SUPPORTED CO; GENERATION; NABH4; NANOPARTICLES; EFFICIENT; EVOLUTION; CARBON;
D O I
10.15251/DJNB.2023.183.899
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In recent years, the effective hydrogen release from hydrogen storage materials has attracted extensive attention. In this work, CoCl2 & BULL;6H2O (Cobalt chloride hexahydrate, CCH), a low cost and easily available catalyst, was successfully used to catalyze the hydrolysis of NaBH4-NH3BH3 composite (xSB-AB, x is the molar ratio of SB to AB). The results show that the synergistic effect produced by ball milling is beneficial to improve the hydrogen release performance of xSB-AB hydrolysis. This work not only advances the understanding of the synergistic effect of SB and AB, but also provides a basis for using low-cost catalysts to improve the hydrolysis performance of xSB-AB.
引用
收藏
页码:899 / 913
页数:15
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