Construction of magnetic hydroxyl group-enriched hyper cross-linked polymers with functional triazine as the core for efficient enrichment of plant growth regulators

The determination of trace plant growth regulators (PGRs) residues in water and food samples make it crucial to develop novel sample pretreatment methods for the enrichment of PGRs. Herein, a novel magnetic hyper crosslinked polymer (M-CTT-9OH-HCP) was constructed and served as a magnetic adsorbent for the efficient extraction of some PGRs from water, watermelon, tomatoes, and milk samples for the first time. Combined with high performance liquid chromatography-fluorescence detection (HPLC-FLD), the established method presented a good linearity (0.03-60.0 ng g-1 (ng mL-1), (r) >= 0.9973), satisfactory accuracy with method recoveries (83.0%-119%) and acceptable precision with the intra-day and inter-day variations (expressed as the relative standard deviations (RSDs) <= 9.8%). The limits of detection (LODs) and limits of quantitation (LOQs) were in the range of 0.01-1.50 and 0.03-5.00 ng g-1/ ng mL-1. The results show that the established method is sensitive and efficient for the determination of PGRs in real samples.