Graphene oxide@Fe3o4@Tungstate modified ionic liquid as a novel electrode material for high- performance supercapacitor

被引:37
作者
Dalvand, Samad [1 ]
Khoushab, Zahra [2 ]
Mousavi-Khoshdel, S. Morteza [1 ]
Ghafuri, Hossein [2 ]
Zand, Hamid Reza Esmaili [2 ]
Omidvar, Mehran [3 ]
机构
[1] Iran Univ Sci & Technol, Fac Chem, Ind Electrochem Res Lab, Tehran 1684613114, Iran
[2] Iran Univ Sci & Technol, Dept Chem, Catalysts & Organ Synth Res Lab, Tehran 1684613114, Iran
[3] Acad Ctr Educ Culture & Res ACECR, Iranian Res & Dev Ctr Chem Ind IRDCI, Karaj, Iran
关键词
Supercapacitor; Electrode materials; Ionic liquid; Nanocomposite; NANOFIBER; CARBON; NANOCOMPOSITES; TEMPERATURE; NANOSHEETS; FIBERS; ANODE;
D O I
10.1016/j.ijhydene.2022.12.026
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, using Fe3O4, graphene oxide (GO), Na2WO4, and ionic liquid (IL), GO@ Fe3O4-IL-W as a novel nanocomposite has been synthesized to obtain a high-performance super-capacitor. The morphologies and structures of materials have been characterized by Fourier-transform infrared (FT-IR) spectroscopy, thermal gravimetric analysis (TGA), X-ray diffraction (XRD), vibrating-sample magnetometer (VSM), scanning electron microscopy (FESEM), and energy diffraction X-ray (EDX) analysis. The behavior of electrochemical and supercapacitive nanocomposite has been investigated using cyclic voltammetry (CV), gal-vanostatic charge/discharge (GCD), and electrochemical impedance spectroscopy (EIS). The fabricated electrode material exhibited high specific capacitance (332.45 F/g at 0.2 A/g) and excellent electrochemical performance based on the cyclic stability (capacitance retention of 91.3% after 10,000 cycles). Furthermore, a symmetric supercapacitor device based on GO@ Fe3O4-IL-W was successfully assembled and an energy density of 7.38 Wh/kg at a power density of 40 W/kg has been obtained. Consequently, the GO@ Fe3O4-IL-W nano -composite electrode material is expected to be a promising material for supercapacitor applications and other energy devices. (c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:10098 / 10107
页数:10
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