Use of cellulose fiber from Jipijapa (Carludovicapalmata) as fillers in corn starch-based biocomposite film

被引:2
|
作者
Perez-Pacheco, Emilio [1 ]
Rios-Soberanis, Carlos Rolando [2 ]
Mina-Hernandez, Jose H. [3 ]
Moo-Huchin, Victor Manuel [4 ]
机构
[1] Tecnol Nacl Mexico, Cuerpo Acad Bioproc, Campus Inst Tecnol Super Calkini,Ave Ah Canul, Calkini 24900, Campeche, Mexico
[2] Ctr Invest Cient Yucatan AC, Calle 43 130 X 32 & 34, Merida 97205, Yucatan, Mexico
[3] Univ Valle, Grp Mat Compuestos, Calle 13 100-00, Cali 76001, Colombia
[4] Tecnol Nacl Mexico, Inst Tecnol Merida, Merida 97118, Yucatan, Mexico
关键词
Thermoplastic starch; Carludovicapalmate; Biocomposite films; Structure characterization; Mechanical properties; REINFORCED THERMOPLASTIC STARCH; NATURAL-FIBER; MECHANICAL-PROPERTIES; THERMAL-PROPERTIES; BIO-COMPOSITES; BLENDS; NANOCOMPOSITES; EXTRACTION; BEHAVIOR; SORPTION;
D O I
10.1007/s13726-023-01244-y
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The advancement in design and mechanical performance of biocomposites has expanded significantly towards developing polymers with specific capabilities. In this research, natural cellulose fiber from the Jipijapa palm (Carludovicapalmata) (CP) was used as reinforcement in a biocomposite material (BC) of thermoplastic starch (TPS) based on corn starch to describe cost-effective ways to improve the mechanical toughness and durability of BCs, while evaluating the potential as substitutes for petroleum-based plastics in industries such as packaging, electronic, automotive, aerospace and construction. The volumetric fraction of cellulose used in the manufacture of corn TPS composites were 10, 20 and 30% w/w by compression molding. The thermostability of the biocomposites was determined by thermogravimetric analysis. SEM images revealed residues of polymeric matrix adhered to the fiber surface suggesting good interfacial adhesion between fiber and matrix. The results of the solubility analysis performed on the biocomposites showed an increase in the water solubility of the TPS matrix. Likewise, the BC reached their hygrothermal stability after 10 days of exposure in humidity environments between 55 and 75% at 25 C-degrees. The incorporation of cellulose fibers in the corn TPS biocomposite generated an increase in gelatinization temperature compared to TPS alone. Based on their excellent properties, biocomposites made up from cellulose fiber embedded in a corn TPS matrix, are suitable for various industrial applications, at a lower cost.
引用
收藏
页码:157 / 168
页数:12
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