High-Performance MEMS Oxygen Sensors Based on Au/TiO2 Films

被引:4
作者
Jiao, Mingzhi [1 ,2 ,3 ]
Zhao, Xiaohu [2 ,3 ]
He, Xinjian [1 ]
Wang, Gang [2 ,3 ]
Zhang, Wei [4 ]
Rong, Qian [4 ]
Nguyen, Duchoa [5 ]
机构
[1] China Univ Min & Technol, Sch Safety Engn, Xuzhou 221116, Peoples R China
[2] China Univ Min & Technol, State & Local Joint Engn Lab Percept Mine, Xuzhou 221116, Peoples R China
[3] China Univ Min & Technol, Sch Informat & Control Engn, Xuzhou 221116, Peoples R China
[4] Micro & Nano Sensing Corp, Hefei 230001, Peoples R China
[5] Hanoi Univ Sci & Technol, Int Training Inst Mat Sci, Hanoi 100000, Vietnam
关键词
oxygen sensor; titanium dioxide; gold decoration; microhotplate; thin films; THIN-FILMS;
D O I
10.3390/chemosensors11090476
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
High-performance microelectromechanical system (MEMS) oxygen sensors were realized by successful preparation of Au nanofilms over TiO2 thin films through successive sputtering on commercial MEMS microhotplates. Oxygen sensing performance of 3 and 6 nm thick Au over TiO2 thin films were compared with that of pure TiO2 thin films. It was shown that 6 nm thick Au over TiO2 thin films have the best sensitivity toward oxygen. The prepared TiO2 thin films were characterized using SEM, EDS, XPS, and a gas testing instrument. The results show that Au decoration has little influence on the surface morphologies of TiO2 thin films. However, Au decoration has a strong influence on the surface properties of the composite films. The favorable performance of 6 nm Au-doped TiO2 thin films is attributed to factors such as catalytical performance, height of Schottky contact, and number of oxygen vacancies. This work makes contributions to low power consumption and high-performance oxygen sensors for Internet of Things applications.
引用
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页数:8
相关论文
共 24 条
[1]   N-doping effects on the oxygen sensing of TiO2 films [J].
Buono, C. ;
Desimone, M. ;
Schipani, F. ;
Aldao, C. M. ;
Vignatti, C. I. ;
Morgade, C. I. N. ;
Cabeza, G. F. ;
Garetto, T. F. .
JOURNAL OF ELECTROCERAMICS, 2018, 40 (01) :72-77
[2]   Oxygen Sensing of Pt/PEO-TiO2 in Humid Atmospheres at Moderate Temperatures [J].
Engelkamp, Bernd ;
Schierbaum, Klaus .
SENSORS, 2021, 21 (07)
[3]   Recent developments of nanomaterials-based conductive type methane sensors [J].
Jiao, Ming-Zhi ;
Chen, Xiao-Yu ;
Hu, Ke-Xiang ;
Qian, De-Yu ;
Zhao, Xiao-Hu ;
Ding, En-Jie .
RARE METALS, 2021, 40 (06) :1515-1527
[4]   On-chip growth of patterned ZnO nanorod sensors with PdO decoration for enhancement of hydrogen-sensing performance [J].
Jiao, Mingzhi ;
Nguyen Van Duy ;
Nguyen Viet Chien ;
Nguyen Duc Hoa ;
Nguyen Van Hieu ;
Hjort, Klas ;
Hugo Nguyen .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (25) :16294-16304
[5]   UV assisted room temperature oxygen sensors using titanium dioxide nanostructures [J].
Jyothilal, Hiran ;
Shukla, Gaurav ;
Walia, Sunil ;
Bharath, S. P. ;
Angappane, S. .
MATERIALS RESEARCH BULLETIN, 2021, 140
[6]   Preparation of Au nanoparticles modified TiO2 nanotube array sensor and its application as chemical oxygen demand sensor [J].
Liang, Longqi ;
Yin, Jiao ;
Bao, Jinpeng ;
Cong, Linchuan ;
Huang, Weimin ;
Lin, Haibo ;
Shi, Zhan .
CHINESE CHEMICAL LETTERS, 2019, 30 (01) :167-170
[7]   Amorphous TiO2 nanotube arrays for low-temperature oxygen sensors [J].
Lu, Hao Feng ;
Li, Feng ;
Liu, Gang ;
Chen, Zhi-Gang ;
Wang, Da-Wei ;
Fang, Hai-Tao ;
Lu, Gao Qing ;
Jiang, Zhou Hua ;
Cheng, Hui-Ming .
NANOTECHNOLOGY, 2008, 19 (40)
[8]   Room-temperature gas sensing of laser-modified anatase TiO2 decorated with Au nanoparticles [J].
Mintcheva, Neli ;
Srinivasan, Parthasarathy ;
Rayappan, John Bosco Balaguru ;
Kuchmizhak, Aleksandr A. ;
Gurbatov, Stanislav ;
Kulinich, Sergei A. .
APPLIED SURFACE SCIENCE, 2020, 507
[9]   Oxygen detection using nanostructured TiO2 thin films obtained by the molecular layering method [J].
Mokrushin, Artem S. ;
Simonenko, Elizaveta P. ;
Simonenko, Nikolay P. ;
Akkuleva, Karma T. ;
Antipov, Vladymir V. ;
Zaharova, Natalia, V ;
Malygin, Anatolii A. ;
Bukunov, Kirill A. ;
Sevastyanov, Vladimir G. ;
Kuznetsov, Nikolay T. .
APPLIED SURFACE SCIENCE, 2019, 463 (197-202) :197-202
[10]   Gas-sensing properties of nanostructured CO2-xZrO2 thin films obtained by the sol-gel method [J].
Mokrushin, Artem S. ;
Simonenko, Elizaveta P. ;
Simonenko, Nikolay P. ;
Bukunov, Kirill A. ;
Sevastyanov, Vladimir G. ;
Kuznetsov, Nikolay T. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 773 :1023-1032