Naphthoquinone-intercalated vanadium oxide for high-performance zinc-ion battery

被引：8
作者：
Guo, Ying [1 ]
Liu, Yang [1 ]
Li, Kai [1 ]
Gong, Yun [1 ]
机构：
[1] Chongqing Univ, Coll Chem & Chem Engn, Dept Appl Chem, Chongqing 401331, Peoples R China
来源：
JOURNAL OF SOLID STATE ELECTROCHEMISTRY | 2023年 / 27卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Naphthoquinone; Intercalant; Vanadium oxide; High-performance; Zinc-ion battery; POLYANILINE; VANADATE; CATHODE; V2O5;
D O I：
10.1007/s10008-023-05542-6
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
(2, 3-DN)(0.23)V2O5 center dot 0.22H(2)O (DN = dinaphthoquinone) nanosheets with rich oxygen vacancies (abbreviated as (2, 3-DN)-VO) were synthesized by a facile one-step solvothermal method. Rietveld refinement illustrates the successful intercalation of 2, 3-DN into the layered vanadium oxide. (2, 3-DN)-VO can deliver a high specific capacity of 440 mAh g(-1) at 0.1 A g(-1) with a capacity retention of 92.6% over 2300 discharge/charge cycles at 10 A g (-1) when used as zinc-ion battery cathode. It benefits from the dual-activity of naphthoquinone and vanadium oxide. Meanwhile, the encapsulation of naphthoquinone into the interlayer channel of vanadium oxide not only can expand the interstitial spacing for the diffusion of Zn2+, but also prevent the dissolution of the organic species into the electrolyte.
引用
收藏
页码：2579 / 2592
页数：14
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