Synthesis and characterization of highly efficient Te-doped Mn3O4 and s-g-C3N4/Te- Mn3O4 nanocomposites as an excellent antimicrobial and photocatalytic agent

被引:17
作者
Umar, Misbah [1 ]
Ajaz, Humayun [1 ]
Javed, Mohsin [2 ]
Iqbal, Shahid [3 ]
Khan, Muhammad Shuaib [4 ]
Alhujaily, Ahmad [5 ]
Awwad, Nasser S. [6 ]
Ibrahium, Hala A. [7 ]
机构
[1] Univ Engn & Technol, Dept Chem, Lahore 54890, Pakistan
[2] Univ Management & Technol, Sch Sci, Dept Chem, Lahore 54770, Pakistan
[3] Natl Univ Sci & Technol NUST, Sch Nat Sci SNS, Dept Chem, H 12, Islamabad 46000, Pakistan
[4] Chinese Acad Sci, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys,iChEM, Dalian 116023, Liaoning, Peoples R China
[5] Taibah Univ, Coll Sci, Biol Dept, Al Madinah Al Munawarah 41477, Saudi Arabia
[6] King Khalid Univ, Fac Sci, Chem Dept, POB 9004, Abha 61413, Saudi Arabia
[7] King Khalid Univ, Fac Sci, Biol Dept, POB 9004, Abha 61413, Saudi Arabia
关键词
Tetragonal hausmanite; Co-precipitation; Nanoparticles; Antibacterial activity; OXIDE NANOPARTICLES; GRAPHENE OXIDE; ENHANCED PHOTOCATALYSIS; ANTIBACTERIAL ACTIVITY; SELECTIVE OXIDATION; ZINC-OXIDE; TOXICITY; ZNO; NANOFIBERS; MECHANISM;
D O I
10.1016/j.inoche.2023.111353
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This work aims to synthesize manganese oxide nanoparticles (Mn3O4NPs) using a co-precipitation method and analyzed them through XRD, SEM and FT-IR. The XRD analysis confirmed the tetragonal hausmanite structure of the Mn3O4 NPs, while SEM revealed an average particle size of 9-20 nm. Kinetic studies demonstrated the efficient photooxidation of methylene blue with first-order kinetics under UV or visible light. Degradation efficiencies varied between 82% and 93% depending on the light source. Furthermore, we used the zone inhibition approach to assess the antibacterial potency of various Mn3O4 NP contents alongside human pathogenic bacteria, namely Escherichia coli and Staphylococcus aureus. The results of the qualitative antibacterial tests revealed that E. coli, a Gram-negative bacterium, is more sensitive to Mn3O4 NPs than are Gram-positive bacteria, with a maximum zone diameter of 28 mm (S. aureus). Alternatively, it was determined that S-g-C3N4/Te-Mn2O3 had the maximum antifungal activity against Alternaria solani at 28.9 mm and against. Colletotrichum gloeosporioides at 47.3 mm.
引用
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页数:9
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