Kinetics for the reaction of Criegee intermediate CH2OO with n-butyraldehyde and its atmospheric implications

The Criegee intermediates (CIs), formed through ozone oxidation of unsaturated hydrocarbons, can undergo reactions with various carbonyl compounds in the atmosphere. In this study, we have investigated the 1,3-cycloaddition reaction of n-butyraldehyde with the simplest Criegee intermediate, CH2OO, using the OH laser-induced fluorescence (LIF) method. The experiments were conducted over a temperature and pressure range of 283-318 K and 5-100 Torr, respectively. Our results reveal that the bimolecular rate constant of the reaction is dependent on both temperature and pressure. Specifically, the measured rate constants at 100 Torr are (3.51 & PLUSMN; 0.63), (2.97 & PLUSMN; 0.53), (2.70 & PLUSMN; 0.49), and (2.52 & PLUSMN; 0.45) x 10-12 cm3 molecule- 1 s-1 at temperatures of 283, 298, 308, and 318 K, respectively, with a total error of 18%. By fitting the pressure-dependent rate constants according to the Lindemann mechanism, we obtained a high-pressure limit rate constant of (3.05 & PLUSMN; 0.55) x 10-12 cm3 molecule-1 s-1 at 298 K. The Arrhenius plot of the temperature-dependent rate constants yields an activation energy of (-1.71 & PLUSMN; 0.30) kcal mol- 1 and a pre-exponential factor of (1.66 & PLUSMN; 0.24) x 10-13 cm-3 s-1 (total error). Furthermore, our findings indicate that the title reaction exhibits a more pronounced temperature-dependent effect compared to that of CH2OO with water dimer and SO2, as well as that of OH with n-butyraldehyde. This observation suggests that the significance of title reaction in the atmosphere increases at lower temperature.