Radical-promoted single-unit monomer insertion (SUMI) [ aka. reversible-deactivation radical addition (RDRA)]

被引：22

作者：

Boyer, Cyrille ^{[1
]}

Kamigaito, Masami ^{[2
]}

Satoh, Kotaro ^{[3
]}

Moad, Graeme ^{[4
]}

机构：

[1] UNSW Australia, Cluster Adv Macromol Design CAMD, Sydney, NSW 2052, Australia

[2] Nagoya Univ, Grad Sch Engn, Dept Mol & Macromol Chem, Furo Cho,Chikusa Ku, Nagoya 4648603, Japan

[3] Tokyo Inst Technol, Sch Mat Chem Technol, Dept Chem Sci & Engn, 2-12-1 Ookayama,Meguro Ku, Tokyo 1528550, Japan

[4] CSIRO Mfg, Clayton, Vic 3168, Australia

来源：

PROGRESS IN POLYMER SCIENCE | 2023年 / 138卷

基金：

澳大利亚研究理事会;

关键词：

TERT-BUTOXY RADICALS; LIVING CATIONIC-POLYMERIZATION; SEQUENCE-REGULATED OLIGOMERS; RAFT-MEDIATED POLYMERIZATION; BARTON-MCCOMBIE DEOXYGENATION; INITIATION MECHANISMS; CHAIN-TRANSFER; METHYL-METHACRYLATE; MOLECULAR-WEIGHT; BLOCK-COPOLYMERS;

D O I：

10.1016/j.progpolymsci.2023.101648

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We survey progress in the development of the processes for radical-promoted single-unit monomer in-sertion (SUMI) or reversible deactivation radical addition (RDRA), focussing on aminoxyl-[nitroxide-] me-diated SUMI (NM-SUMI), reversible-addition-fragmentation chain transfer-SUMI (RAFT-SUMI) , atom -transfer radical addition (ATRA). Radical-promoted thiol-ene processes are also briefly discussed. We de-tail the strategies for achieving selectivity with respect to single unit insertion vs oligomerization and look critically at progress towards discrete oligomer synthesis by consecutive SUMI reactions. We exam-ine the use of SUMI to install alpha-, omega- or mid-chain-functionality in RDRP-synthesized polymers. Finally, we examine the prospects for using radical-promoted SUMI in the synthesis of sequence-defined poly-mers where monomer placement is precisely defined to the level of the individual monomer units in the polymer chain.(c) 2023 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license ( http://creativecommons.org/licenses/by-nc-nd/4.0/ )

引用

页数：42

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