Electrochemical oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid catalyzed by bio-inspired NiMn layered double hydroxide

被引：5
作者：
Bao, Yide-Rigen [1 ]
Duan, Yu [1 ]
Na, Yong [1 ]
机构：
[1] Harbin Inst Technol, Sch Chem & Chem Engn, Harbin 150001, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2023年 / 11卷 / 35期
关键词：
OXYGEN EVOLUTION; BIOMASS; EFFICIENT; WATER;
D O I：
10.1039/d3ta03408a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The conversion of 5-hydroxymethylfurfural (HMF) into value-added chemicals represents a sustainable bridge toward renewable carbon sources. Inspired by the function of the manganese framework in the active site of the oxygen evolving complex (OEC) in natural photosynthesis, Ni1Mn5-LDH was developed as the most efficient Ni-based electrocatalyst for HMF oxidation to FDCA among the reported materials. A faradaic efficiency of 97% was achieved at 1.4 V (vs. RHE), resulting in FDCA production in a yield of 94.72%. An insight into the reaction pathway indicated that the oxidation of the CH2OH group to the CHO group was the rate-limiting step during HMF oxidation. The conversion of 5-hydroxymethylfurfural (HMF) into value-added chemicals represents a sustainable bridge toward renewable carbon sources.
引用
收藏
页码：18668 / 18671
页数：4
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  • [1] Electrocatalytic Oxidation of 5-(Hydroxymethyl)furfural Using High-Surface-Area Nickel Boride
    Barwe, Stefan
    Weidner, Jonas
    Cychy, Steffen
    Morales, Dulce M.
    Dieckhofer, Stefan
    Hiltrop, Dennis
    Masa, Justus
    Muhler, Martin
    Schuhmann, Wolfgang
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (35) : 11460 - 11464
  • [2] Electrochemical Oxidation of HMF via Hydrogen Atom Transfer and Hydride Transfer on NiOOH and the Impact of NiOOH Composition
    Bender, Michael T.
    Choi, Kyoung-Shin
    [J]. CHEMSUSCHEM, 2022, 15 (13)
  • [3] Electronic structure of the oxygenevolving complex in photosystem II prior to O-O bond formation
    Cox, Nicholas
    Retegan, Marius
    Neese, Frank
    Pantazis, Dimitrios A.
    Boussac, Alain
    Lubitz, Wolfgang
    [J]. SCIENCE, 2014, 345 (6198) : 804 - 808
  • [4] THE ELECTROCHEMICAL OXIDATION OF 5-HYDROXYMETHYLFURFURAL WITH THE NICKEL-OXIDE HYDROXIDE ELECTRODE
    GRABOWSKI, G
    LEWKOWSKI, J
    SKOWRONSKI, R
    [J]. ELECTROCHIMICA ACTA, 1991, 36 (13) : 1995 - 1995
  • [5] Tuning the Relative Stability and Reactivity of Manganese Dioxygen and Peroxo Intermediates via Systematic Ligand Modification
    Kovacs, Julie A.
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2015, 48 (10) : 2744 - 2753
  • [6] Catalysis for biomass and CO2 use through solar energy: opening new scenarios for a sustainable and low-carbon chemical production
    Lanzafame, Paola
    Centi, Gabriele
    Perathoner, Siglinda
    [J]. CHEMICAL SOCIETY REVIEWS, 2014, 43 (22) : 7562 - 7580
  • [7] Catalytic Transformation of Lignin for the Production of Chemicals and Fuels
    Li, Changzhi
    Zhao, Xiaochen
    Wang, Aiqin
    Huber, George W.
    Zhang, Tao
    [J]. CHEMICAL REVIEWS, 2015, 115 (21) : 11559 - 11624
  • [8] Ultrathin NiMn-LDH nanosheet structured electrocatalyst for enhanced electrocatalytic urea oxidation
    Liu, Guoqiang
    Huang, Cheng
    Yang, Zeheng
    Su, Jianhui
    Zhang, Weixin
    [J]. APPLIED CATALYSIS A-GENERAL, 2021, 614
  • [9] Electrochemical Oxidation of 5-Hydroxymethylfurfural with NiFe Layered Double Hydroxide (LDH) Nanosheet Catalysts
    Liu, Wu-Jun
    Dang, Lianna
    Xu, Zhuoran
    Yu, Han-Qing
    Jin, Song
    Huber, George W.
    [J]. ACS CATALYSIS, 2018, 8 (06): : 5533 - 5541
  • [10] Faceted Branched Nickel Nanoparticles with Tunable Branch Length for High-Activity Electrocatalytic Oxidation of Biomass
    Poerwoprajitno, Agus R.
    Gloag, Lucy
    Watt, John
    Cychy, Steffen
    Cheong, Soshan
    Kumar, Priyank V.
    Benedetti, Tania M.
    Deng, Chen
    Wu, Kuang-Hsu
    Marjo, Christopher E.
    Huber, Dale L.
    Muhler, Martin
    Gooding, J. Justin
    Schuhmann, Wolfgang
    Wang, Da-Wei
    Tilley, Richard D.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (36) : 15487 - 15491
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