Enhancing Interplanar Spacing in V2O3/V3O7 Heterostructures to Optimize Cathode Efficiency for Zn-Ion Batteries

被引:10
作者
Selvam, Tharani [1 ]
Dhinasekaran, Durgalakshmi [3 ]
Subramanian, Balakumar [2 ]
Rajendran, Ajay Rakkesh [1 ]
机构
[1] SRM Inst Sci & Technol, Fac Engn & Technol, Dept Phys & Nanotechnol, Funct Nanomat FuN Lab, Kattankulathur 603203, Tamil Nadu, India
[2] Univ Madras, Natl Ctr Nanosci & Nanotechnol, Chennai 600025, Tamil Nadu, India
[3] Anna Univ, Dept Med Phys, Chennai 600025, Tamil Nadu, India
关键词
PERFORMANCE; STORAGE; CARBON;
D O I
10.1021/acs.jpclett.3c03590
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The improvement of sophisticated cathode materials plays a major role in boosting the efficiency of Zn-ion batteries. These batteries have garnered considerable interest as a result of their excellent energy density and the promise of cost-effective solutions for energy storage. In this work, we present a novel approach to progress the electrochemical investigation of Zn-ion batteries by expanding the interplanar distance of layered hydrated V2O3/V3O7 heterostructure nanosheets. Electrochemical investigations were conducted to assess the effectiveness of the stacked hydrated V2O3/V3O7 heterostructure as a cathode component for Zn-ion batteries. The expanded interplanar space as a result of the introduction of water molecules facilitates the insertion/extraction of Zn ions, leading to significantly enhanced electrochemical characteristics. The layered hydrated V2O3/V3O7 heterostructure exhibited an impressive specific capacity of 330 mAh g(-1) at a current density of 0.1 A g(-1), maintaining a capacity retention of approximately 92.3% and a coulombic efficiency of 95.8% even after 2000 cycles.
引用
收藏
页码:1338 / 1346
页数:9
相关论文
共 41 条
[31]   Ultralong cycle stability of aqueous zinc-ion batteries with zinc vanadium oxide cathodes [J].
Wang, Lulu ;
Huang, Kuo-Wei ;
Chen, Jitao ;
Zheng, Junrong .
SCIENCE ADVANCES, 2019, 5 (10)
[32]   Crystallographic engineering of Zn anodes for aqueous batteries [J].
Wu, Shuang ;
Hu, Zhenglin ;
He, Pan ;
Ren, Lingxiao ;
Huang, Jiaxing ;
Luo, Jiayan .
ESCIENCE, 2023, 3 (03)
[33]   Unraveling the role of structural water in bilayer V2O5 during Zn2+-intercalation: insights from DFT calculations [J].
Wu, Tao ;
Zhu, Kaiyue ;
Qin, Changyong ;
Huang, Kevin .
JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (10) :5612-5620
[34]   Boosting proton storage in layered vanadium oxides for aqueous zinc-ion batteries [J].
Wu, Tzu-Ho ;
Lin, Wei-Sheng .
ELECTROCHIMICA ACTA, 2021, 394
[35]   Using Self Organizing Maps to Achieve Lithium-Ion Battery Cells Multi-Parameter Sorting Based on Principle Components Analysis [J].
Xia, Bizhong ;
Yang, Yadi ;
Zhou, Jie ;
Chen, Guanghao ;
Liu, Yifan ;
Wang, Huawen ;
Wang, Mingwang ;
Lai, Yongzhi .
ENERGIES, 2019, 12 (15)
[36]   Water-Lubricated Intercalation in V2O5•nH2O for High-Capacity and High-Rate Aqueous Rechargeable Zinc Batteries [J].
Yan, Mengyu ;
He, Pan ;
Chen, Ying ;
Wang, Shanyu ;
Wei, Qiulong ;
Zhao, Kangning ;
Xu, Xu ;
An, Qinyou ;
Shuang, Yi ;
Shao, Yuyan ;
Mueller, Karl T. ;
Mai, Liqiang ;
Liu, Jun ;
Yang, Jihui .
ADVANCED MATERIALS, 2018, 30 (01)
[37]   Organic Molecular Intercalated V3O7•H2O with High Operating Voltage for Long Cycle Life Aqueous Zn-Ion Batteries [J].
Zhang, Mingying ;
Zhang, Xueqian ;
Dong, Qi ;
Zhang, Shaojie ;
Xu, Zhibin ;
Hou, Zhiguo ;
Qian, Yitai .
ADVANCED FUNCTIONAL MATERIALS, 2023, 33 (31)
[38]   Hydrothermal synthesis, characterization, formation mechanism and electrochemical property of V3O7•H2O single-crystal nanobelts [J].
Zhang, Yifu ;
Liu, Xinghai ;
Xie, Guangyong ;
Yu, Lei ;
Yi, Shengping ;
Hu, Mingjie ;
Huang, Chi .
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2010, 175 (02) :164-171
[39]   Forming bubble-encapsulated double-shelled hollow spheres towards fast kinetics and superior high rate performance for aqueous rechargeable Zn-ion batteries [J].
Zhou, Fangshuo ;
Lin, Yutong ;
Li, Ting ;
Zhang, Sen ;
Deng, Chao .
JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (17) :10589-10600
[40]   Direct Detection and Visualization of the H+ Reaction Process in a VO2 Cathode for Aqueous Zinc-Ion Batteries [J].
Zuo, Shiyong ;
Liu, Jun ;
He, Weixin ;
Osman, Sahar ;
Liu, Zhengbo ;
Xu, Xijun ;
Shen, Jiadong ;
Jiang, Wei ;
Liu, Jiangwen ;
Zeng, Zhiyuan ;
Zhu, Min .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2021, 12 (30) :7076-7084