Enhancing Interplanar Spacing in V2O3/V3O7 Heterostructures to Optimize Cathode Efficiency for Zn-Ion Batteries

被引:10
作者
Selvam, Tharani [1 ]
Dhinasekaran, Durgalakshmi [3 ]
Subramanian, Balakumar [2 ]
Rajendran, Ajay Rakkesh [1 ]
机构
[1] SRM Inst Sci & Technol, Fac Engn & Technol, Dept Phys & Nanotechnol, Funct Nanomat FuN Lab, Kattankulathur 603203, Tamil Nadu, India
[2] Univ Madras, Natl Ctr Nanosci & Nanotechnol, Chennai 600025, Tamil Nadu, India
[3] Anna Univ, Dept Med Phys, Chennai 600025, Tamil Nadu, India
关键词
PERFORMANCE; STORAGE; CARBON;
D O I
10.1021/acs.jpclett.3c03590
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The improvement of sophisticated cathode materials plays a major role in boosting the efficiency of Zn-ion batteries. These batteries have garnered considerable interest as a result of their excellent energy density and the promise of cost-effective solutions for energy storage. In this work, we present a novel approach to progress the electrochemical investigation of Zn-ion batteries by expanding the interplanar distance of layered hydrated V2O3/V3O7 heterostructure nanosheets. Electrochemical investigations were conducted to assess the effectiveness of the stacked hydrated V2O3/V3O7 heterostructure as a cathode component for Zn-ion batteries. The expanded interplanar space as a result of the introduction of water molecules facilitates the insertion/extraction of Zn ions, leading to significantly enhanced electrochemical characteristics. The layered hydrated V2O3/V3O7 heterostructure exhibited an impressive specific capacity of 330 mAh g(-1) at a current density of 0.1 A g(-1), maintaining a capacity retention of approximately 92.3% and a coulombic efficiency of 95.8% even after 2000 cycles.
引用
收藏
页码:1338 / 1346
页数:9
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