Facile Synthesis of Porous ZnCo2O4 Nanorod for Efficient Electrochemical Degradation of Methylene Blue

被引:3
作者
Chen, Caoyue [1 ]
Liu, Lin [1 ]
Xing, Jinjuan [1 ]
Zhang, He [2 ,3 ]
Qian, Jianhua [4 ]
Xu, Jiasheng [4 ]
机构
[1] Bohai Univ, Coll Chem & Chem Engn, Ctr Expt Management, Liaoning Prov Key Lab Synth & Applicat Funct Cpds, 19 Scitech Rd, Jinzhou 121013, Liaoning, Peoples R China
[2] Northeastern Univ, Inst Mat Phys & Chem, Sch Mat Sci & Engn, 11,Ave 3,Wenhua Rd, Shenyang 110004, Liaoning, Peoples R China
[3] Northeastern Univ, Key Lab Anisotropy & Texture Mat, Minist Educ, 11,Ave 3,Wenhua Rd, Shenyang 110004, Liaoning, Peoples R China
[4] Liaoning Univ Petr & Chem Technol, Coll Chem Chem Engn & Environm Engn, 1, West Dandong Rd, Fushun 113001, Liaoning, Peoples R China
基金
中国国家自然科学基金;
关键词
ZnCo2O4; Porous nanorods; Electrocatalysis; MB; OXYGEN EVOLUTION REACTION; WASTE-WATER; CATALYTIC-ACTIVITY; OXIDATION; PERFORMANCE; ELECTRODES; SURFACE; DECOMPOSITION; MICROSPHERES; FABRICATION;
D O I
10.1007/s10562-023-04376-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This study employs a simple and feasible approach for fabricating the porous ZnCo2O4 catalyst with excellent electrochemical activity. We offer insight into the excellent performance of these catalysts by coupling electrochemical measurements with physical characterization methods. These embrace electron microscopy to investigate the morphological structure of the porous catalysts, cyclic voltammetry (CV) to determine the electrochemically active surface area of catalyst materials, linear sweep voltammetry (LSV) to evaluate the oxygen evolution potential (OEP), and electrochemical degradation experiment to assess the degradation performance. ZnCo2O4 porous catalyst exhibits durable stability and high OEP, and provides a large active surface and sufficient numbers of active sites for electrochemical reactions. The ZnCo2O4 porous catalyst can be anticipated as a highly active electrode material for wastewater treatment. This study provides a viable strategy for developing highly active and stable electrode materials on electrochemical applications. [GRAPHICS] .
引用
收藏
页码:1112 / 1125
页数:14
相关论文
共 67 条
[1]   Mesoporous MnCo2O4, NiCo2O4, and ZnCo2O4 Thin-Film Electrodes as Electrocatalysts for the Oxygen Evolution Reaction in Alkaline Solutions [J].
Amirzhanova, Assel ;
Akmansen, Nesibe ;
Karakaya, Irmak ;
Dag, Omer .
ACS APPLIED ENERGY MATERIALS, 2021, 4 (03) :2769-2785
[2]   The Pitfalls of Using Potentiodynamic Polarization Curves for Tafel Analysis in Electrocatalytic Water Splitting [J].
Anantharaj, Sengeni ;
Noda, Suguru ;
Driess, Matthias ;
Menezes, Prashanth W. .
ACS ENERGY LETTERS, 2021, 6 (04) :1607-1611
[3]   INNER AND OUTER ACTIVE SURFACE OF RUO2 ELECTRODES [J].
ARDIZZONE, S ;
FREGONARA, G ;
TRASATTI, S .
ELECTROCHIMICA ACTA, 1990, 35 (01) :263-267
[4]   Electrochemical investigations of cobalt-doped LiMn2O4 as cathode material for lithium-ion batteries [J].
Arora, P ;
Popov, BN ;
White, RE .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (03) :807-815
[5]   Homogeneous photodegradation of CI Reactive Blue 4 using a photo-Fenton process under artificial and solar irradiation [J].
Carneiro, Patricia A. ;
Pupo Nogueira, Raquel F. ;
Zanoni, Maria Valnice B. .
DYES AND PIGMENTS, 2007, 74 (01) :127-132
[6]   Industrial wastewater treatment using hydrodynamic cavitation and heterogeneous advanced Fenton processing [J].
Chakinala, Anand G. ;
Gogate, Parag R. ;
Burgess, Arthur E. ;
Bremner, David H. .
CHEMICAL ENGINEERING JOURNAL, 2009, 152 (2-3) :498-502
[7]   Improved bi-functional ORR and OER catalytic activity of reduced graphene oxide supported ZnCo2O4 microsphere [J].
Chakrabarty, Sankalpita ;
Mukherjee, Ayan ;
Su, Wei-Nien ;
Basu, Suddhasatwa .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (03) :1565-1578
[8]   Battery-type and binder-free MgCo2O4-NWs@NF electrode materials for the assembly of advanced hybrid supercapacitors [J].
Chen, Huiyu ;
Liu, Yafei ;
Wu, Runze ;
Liu, Xiaohong ;
Liu, Yan ;
Xu, Chunju .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2022, 47 (35) :15807-15819
[9]   Facile growth of nickel foam-supported MnCo2O4.5 porous nanowires as binder-free electrodes for high-performance hybrid supercapacitors [J].
Chen, Huiyu ;
Du, Xuming ;
Liu, Xiaohong ;
Wu, Runze ;
Li, Yi ;
Xu, Chunju .
JOURNAL OF ENERGY STORAGE, 2022, 50
[10]   Simple preparation of ZnCo2O4 porous quasi-cubes for high performance asymmetric supercapacitors [J].
Chen, Huiyu ;
Du, Xuming ;
Sun, Jiale ;
Mao, Hui ;
Wu, Runze ;
Xu, Chunju .
APPLIED SURFACE SCIENCE, 2020, 515