Soluble organic molecules in samples of the carbonaceous asteroid (162173) Ryugu

被引：137

作者：

Naraoka, Hiroshi ^{[1
]}

Takano, Yoshinori ^{[2
]}

Dworkin, Jason P. ^{[3
]}

Oba, Yasuhiro ^{[4
]}

Hamase, Kenji ^{[5
]}

Furusho, Aogu ^{[45
]}

Ogawa, Nanako O. ^{[2
]}

Hashiguchi, Minako ^{[6
]}

Fukushima, Kazuhiko ^{[7
]}

Aoki, Dan ^{[7
]}

Schmitt-Kopplin, Philippe ^{[8
,9
,10
]}

Aponte, Jose C. ^{[3
]}

Parker, Eric T. ^{[3
]}

Glavin, Daniel P. ^{[3
]}

McLain, Hannah L. ^{[3
,11
,12
]}

Elsila, Jamie E. ^{[3
]}

Graham, Heather V. ^{[3
]}

Eiler, John M. ^{[13
]}

Orthous-Daunay, Francois-Regis ^{[14
]}

Wolters, Cedric ^{[14
]}

Isa, Junko ^{[15
,16
]}

Vuitton, Veronique ^{[14
]}

Thissen, Roland ^{[17
]}

Sakai, Saburo ^{[2
]}

Yoshimura, Toshihiro ^{[2
]}

Koga, Toshiki ^{[2
]}

Ohkouchi, Naohiko ^{[2
]}

Chikaraishi, Yoshito ^{[4
]}

Sugahara, Haruna ^{[18
]}

Mita, Hajime ^{[19
]}

Furukawa, Yoshihiro ^{[20
]}

Hertkorn, Norbert ^{[8
]}

Ruf, Alexander ^{[21
,22
,23
]}

Yurimoto, Hisayoshi ^{[24
]}

Nakamura, Tomoki ^{[20
]}

Noguchi, Takaaki ^{[25
]}

Okazaki, Ryuji ^{[1
]}

Yabuta, Hikaru ^{[26
]}

Sakamoto, Kanako ^{[18
]}

Tachibana, Shogo ^{[18
,27
]}

Connolly, Harold C., Jr. ^{[28
]}

Lauretta, Dante S. ^{[29
]}

Abe, Masanao ^{[18
,30
]}

Yada, Toru ^{[18
]}

Nishimura, Masahiro ^{[18
]}

Yogata, Kasumi ^{[18
]}

Nakato, Aiko ^{[18
]}

Yoshitake, Miwa ^{[18
]}

Suzuki, Ayako ^{[31
]}

Miyazaki, Akiko ^{[18
]}

机构：

[1] Kyushu Univ, Dept Earth & Planetary Sci, Fukuoka 8190395, Japan

[2] Japan Agcy Marine Earth Sci & Technol, Biogeochem Res Ctr, Yokosuka 2370061, Japan

[3] NASA Goddard Space Flight Ctr, Solar Syst Explorat Div, Greenbelt, MD 20771 USA

[4] Hokkaido Univ, Inst Low Temp Sci, Sapporo, Hokkaido 0600189, Japan

[5] Kyushu Univ, Grad Sch Pharmaceut Sci, Fukuoka 8128582, Japan

[6] Nagoya Univ, Grad Sch Environm Studies, Nagoya, Aichi 4648601, Japan

[7] Nagoya Univ, Grad Sch Bioagr Sci, Nagoya, Aichi 4648601, Japan

[8] Helmholtz Munich, Analyt BioGeochem, D-85764 Neuherberg, Germany

[9] Tech Univ Munich, Analyt Lebensmittel Chem, D-85354 Freising Weihenstephan, Germany

[10] Max Planck Inst Extraterr Phys, D-85748 Garching, Germany

[11] NASA Goddard Space Flight Ctr, Ctr Res & Explorat Space Sci & Technol, Greenbelt, MD 20771 USA

[12] Catholic Univ Amer, Dept Phys, Washington, DC 20064 USA

[13] CALTECH, Div Geol & Planetary Sci, Pasadena, CA 91125 USA

[14] Univ Grenoble Alpes, Ctr Natl Rech Sci CNRS, Ctr Natl Etudes Spati, Inst Planetol & Astrophys Grenoble, F-38000 Grenoble, France

[15] Tokyo Inst Technol, Earth Life Sci Inst, Tokyo 1528550, Japan

[16] Chiba Inst Technol, Planetary Explorat Res Ctr, Narashino, Chiba 2750016, Japan

[17] Univ Paris Saclay, Inst Chim Phys, CNRS, F-91405 Orsay, France

[18] Japan Aerosp Explorat Agcy JAXA, Inst Space & Astronaut Sci, Sagamihara 2525210, Japan

[19] Fukuoka Inst Technol, Dept Life Environm & Mat Sci, Fukuoka 8110295, Japan

[20] Tohoku Univ, Dept Earth Sci, Sendai 9808578, Japan

[21] Univ Aix Marseille, CNRS, Lab Phys Interact Ion & Mol, F-13397 Marseille, France

[22] Ludwig Maximilians Univ Munchen, Dept Chem & Pharm, D-81377 Munich, Germany

[23] Excellence Cluster ORIGINS, D-85748 Garching, Germany

[24] Hokkaido Univ, Dept Earth & Planetary Sci, Sapporo 0600810, Japan

[25] Kyoto Univ, Div Earth & Planetary Sci, Kyoto 6068502, Japan

[26] Hiroshima Univ, Dept Earth & Planetary Syst Sci, Higashihiroshima 7398526, Japan

[27] Univ Tokyo, Dept Earth & Planetary Sci, Tokyo 1130033, Japan

[28] Rowan Univ, Sch Earth & Environm, Dept Geol, Glassboro, NJ 08028 USA

[29] Univ Arizona, Lunar & Planetary Lab, Tucson, AZ 85721 USA

[30] Grad Univ Adv Studies, Sch Phys Sci, Hayama 2400193, Japan

[31] Marine Works Japan Ltd, Yokosuka 2370063, Japan

[32] Univ Aizu, Aizu Res Cluster Space Sci, Aizu Wakamatsu 9658580, Japan

[33] Natl Astron Observ Japan, Res Interior Struct & Evolut Solar Syst Bodies, Mitaka 1818588, Japan

[34] Kobe Univ, Dept Planetol, Kobe 6578501, Japan

[35] Seoul Natl Univ, Dept Phys & Astron, Seoul 08826, South Korea

[36] JAXA, Research & Dev Directorate, Sagamihara 2525210, Japan

[37] Niigata Univ, Fac Sci, Niigata 9502181, Japan

[38] Rikkyo Univ, Dept Phys, Tokyo 1718501, Japan

[39] Ehime Univ, Ctr Data Sci, Matsuyama 7908577, Japan

[40] Univ Laguna, Inst Astrofis Canarias, E-38205 Tenerife, Spain

[41] Kindai Univ, Fac Engn, Higashihiroshima 7392116, Japan

[42] JAXA, JAXA Space Explorat Ctr, Sagamihara 2525210, Japan

[43] Univ Tokyo, Dept Chem, Tokyo 1130033, Japan

[44] Kanagawa Inst Technol, Dept Mech Engn, Atsugi 2430292, Japan

[45] Univ Shizuoka, Sch Pharmaceut Sci, Shizuoka 4228526, Japan

[46] Geol Survey Japan, Natl Inst Adv Ind Sci & Technol, Tsukuba 3058567, Japan

来源：

SCIENCE | 2023年 / 379卷 / 6634期

关键词：

MONOCARBOXYLIC ACIDS; ALIPHATIC-AMINES; MURCHISON METEORITE; PARENT BODY; INTERSTELLAR; CHONDRITE; HYDROCARBONS; EVOLUTION; EMISSION; ORIGINS;

D O I：

10.1126/science.abn9033

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The Hayabusa2 spacecraft collected samples from the surface of the carbonaceous near-Earth asteroid (162173) Ryugu and brought them to Earth. The samples were expected to contain organic molecules, which record processes that occurred in the early Solar System. We analyzed organic molecules extracted from the Ryugu surface samples. We identified a variety of molecules containing the atoms CHNOS, formed by methylation, hydration, hydroxylation, and sulfurization reactions. Amino acids, aliphatic amines, carboxylic acids, polycyclic aromatic hydrocarbons, and nitrogen-heterocyclic compounds were detected, which had properties consistent with an abiotic origin. These compounds likely arose from an aqueous reaction on Ryugu's parent body and are similar to the organics in Ivuna-type meteorites. These molecules can survive on the surfaces of asteroids and be transported throughout the Solar System.

引用

页码：789 / +

页数：11

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