Ruthenium Nanocatalysts Immobilized on DFNS-IL Heterogeneous Catalyst for Hydroformylation of Alkenes with CO2 and H2

被引：4

作者：

Li, Yinyan ^{[1
]}

Song, Shen ^{[2
]}

Sadeghzadeh, Seyed Mohsen ^{[3
]}

机构：

[1] Lvliang Univ, Dept Min Engn, Luliang 033001, Shanxi, Peoples R China

[2] Energy Informat Dispatching Ctr Lvliang City, Luliang 033001, Shanxi, Peoples R China

[3] Islamic Azad Univ, Dept Chem, Neyshabur Branch, Neyshabur, Iran

来源：

CATALYSIS LETTERS | 2023年 / 153卷 / 01期

关键词：

Nanocatalyst; Green chemistry; Hydrogenation; Hydroformylation; DFNS; Carbon dioxide; FIBROUS NANO-SILICA; IONIC LIQUIDS; NANOPARTICLES; CYCLOADDITION; COMPLEX; AZIDES; CARBONYLATIONS; REACTIVITY; REDUCTION; ALKYNES;

D O I：

10.1007/s10562-022-03968-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The current study reports the synthesis of multi-site ionic liquids immobilized on DFNS (DFNS-IL) in an aqueous medium. Hence, the ruthenium nanoparticles (NPs) are well-dispersed over the DFNS-IL (DFNS-IL@Ru). Its catalytic function for hydroformylation of alkenes using CO2/H-2 as a syngas surrogate is described here under mild conditions. Resultants with good to excellent performance were created employing DFNS-IL@Ru nanocatalyst. The structure of the catalyst was specified by a variety of techniques, including FT-IR, XRD, SEM, TGA, AFM, XPS, TEM, and EDX. The stability of the catalytic system was enhanced after releasing a large quantity of DFNS. The recycling state of the catalyst and the procedure of the coupling reactions were repeatedly investigated.

引用

页码：95 / 103

页数：9

共 50 条

[31] Highly efficient photocatalytic reduction of CO2 and H2O to CO and H2 with a cobalt bipyridyl complex
Yao, Ya'nan
Gao, Yan
Ye, Lu
Chen, Hu
Sun, Licheng
JOURNAL OF ENERGY CHEMISTRY, 2018, 27 (02) : 502 - 506
[32] Performance analysis of nanostructured NiO-In2O3/TiO2 catalyst for CO2 photoreduction with H2 in a monolith photoreactor
Tahir, Muhammad
Amin, NorAishah Saidina
CHEMICAL ENGINEERING JOURNAL, 2016, 285 : 635 - 649
[33] Direct formation of dendritic Ag catalyst on a gas diffusion layer for electrochemical CO2 reduction to CO and H2
Ham, Yu Seok
Kim, Myung Jun
Lim, Taeho
Kim, Dong-Kwon
Kim, Soo-Kil
Kim, Jae Jeong
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2018, 43 (24) : 11315 - 11325
[34] Rhodium-Catalyzed Formylation of Aryl Halides with CO2 and H2
Liu, Zhenghui
Yang, Zhenzhen
Yu, Bo
Yu, Xiaoxiao
Zhang, Hongye
Zhao, Yanfei
Yang, Peng
Liu, Zhimin
ORGANIC LETTERS, 2018, 20 (17) : 5130 - 5134
[35] Anion dependent CO/H2 production ratio from CO2 reduction on Au electro-catalyst
Hong, Sujik
Lee, Seunghwa
Kim, Sohaeng
Lee, Jae Kwang
Lee, Jaeyoung
CATALYSIS TODAY, 2017, 295 : 82 - 88
[36] An APXPS Probe of Cu/Pd Bimetallic Catalyst Surface Chemistry of CO2 Toward CO in the Presence of H2O and H2
Leclerc, Maxime
Etxebarria, Ane
Ye, Yifan
Crumlin, Ethan J.
Brisard, Gessie M.
JOURNAL OF PHYSICAL CHEMISTRY C, 2020, 124 (31) : 17085 - 17094
[37] Enhanced CO2 photocatalytic reduction through simultaneously accelerated H2 evolution and CO2 hydrogenation in a twin photoreactor
Xiong, Zhuo
Kuang, Chia-Chien
Lin, Kuan-Yu
Lei, Ze
Chen, Xiaoxiang
Gong, Bengen
Yang, Jianping
Zhao, Yongchun
Zhang, Junying
Xia, Baoyu
Wu, Jeffrey C. S.
JOURNAL OF CO2 UTILIZATION, 2018, 24 : 500 - 508
[38] Aluminium porphyrins catalyse the hydrogenation of CO2 with H2
Kumar, Nitin
Gastelu, Gabriela
Zabransky, Martin
Kukla, Jaroslav
Uranga, Jorge G.
Hulla, Martin
CHEMICAL SCIENCE, 2024, 15 (48) : 20573 - 20581
[39] Catalytic direct hydrocarboxylation of styrenes with CO2 and H2
Jin, Yushu
Caner, Joaquim
Nishikawa, Shintaro
Toriumi, Naoyuki
Iwasawa, Nobuharu
NATURE COMMUNICATIONS, 2022, 13 (01)
[40] Synthesis of ethanol from paraformaldehyde, CO2 and H2
Zhang, Jingjing
Qian, Qingli
Cui, Meng
Chen, Chunjun
Liu, Shuaishuai
Han, Buxing
GREEN CHEMISTRY, 2017, 19 (18) : 4396 - 4401

← 1 2 3 4 5 →