Ruthenium Nanocatalysts Immobilized on DFNS-IL Heterogeneous Catalyst for Hydroformylation of Alkenes with CO2 and H2

被引：4

作者：

Li, Yinyan ^{[1
]}

Song, Shen ^{[2
]}

Sadeghzadeh, Seyed Mohsen ^{[3
]}

机构：

[1] Lvliang Univ, Dept Min Engn, Luliang 033001, Shanxi, Peoples R China

[2] Energy Informat Dispatching Ctr Lvliang City, Luliang 033001, Shanxi, Peoples R China

[3] Islamic Azad Univ, Dept Chem, Neyshabur Branch, Neyshabur, Iran

来源：

CATALYSIS LETTERS | 2023年 / 153卷 / 01期

关键词：

Nanocatalyst; Green chemistry; Hydrogenation; Hydroformylation; DFNS; Carbon dioxide; FIBROUS NANO-SILICA; IONIC LIQUIDS; NANOPARTICLES; CYCLOADDITION; COMPLEX; AZIDES; CARBONYLATIONS; REACTIVITY; REDUCTION; ALKYNES;

D O I：

10.1007/s10562-022-03968-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The current study reports the synthesis of multi-site ionic liquids immobilized on DFNS (DFNS-IL) in an aqueous medium. Hence, the ruthenium nanoparticles (NPs) are well-dispersed over the DFNS-IL (DFNS-IL@Ru). Its catalytic function for hydroformylation of alkenes using CO2/H-2 as a syngas surrogate is described here under mild conditions. Resultants with good to excellent performance were created employing DFNS-IL@Ru nanocatalyst. The structure of the catalyst was specified by a variety of techniques, including FT-IR, XRD, SEM, TGA, AFM, XPS, TEM, and EDX. The stability of the catalytic system was enhanced after releasing a large quantity of DFNS. The recycling state of the catalyst and the procedure of the coupling reactions were repeatedly investigated.

引用

页码：95 / 103

页数：9

共 50 条

[1] Ruthenium Nanocatalysts Immobilized on DFNS-IL Heterogeneous Catalyst for Hydroformylation of Alkenes with CO2 and H2
Yinyan Li
Shen Song
Seyed Mohsen Sadeghzadeh
Catalysis Letters, 2023, 153 : 95 - 103
[2] Chemo- and regioselective hydroformylation of alkenes with CO2/H2 over a bifunctional catalyst
Hua, Kaimin
Liu, Xiaofang
Wei, Baiyin
Shao, Zilong
Deng, Yuchao
Zhong, Liangshu
Wang, Hui
Sun, Yuhan
GREEN CHEMISTRY, 2021, 23 (20) : 8040 - 8046
[3] Regioselective Hydroxymethylation of Alkenes to Linear Alcohols with CO2/H2 Using a Rh/Ru Dual Catalyst
Hua, Kaimin
Liu, Xiaofang
Chen, Junjun
Wei, Baiyin
Wang, Hui
Sun, Yuhan
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2021, 9 (49): : 16741 - 16748
[4] Hydroformylation of Olefins with CO2/H2 and Hydrosilane by Copper/Cobalt Tandem Catalysis
Wu, An-Guo
Ding, Jie
Zhao, Lan
Li, Hong-Ru
He, Liang-Nian
CHEMSUSCHEM, 2024, 17 (16)
[5] Hydrogenation of CO2 to Formate with H2: Transition Metal Free Catalyst Based on a Lewis Pair
Zhao, Tianxiang
Hu, Xingbang
Wu, Youting
Zhang, Zhibing
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (03) : 722 - 726
[6] Amine formylation with CO2 and H2 catalyzed by heterogeneous Pd/PAL catalyst
Dai, Xingchao
Wang, Bin
Wang, Aiqin
Shi, Feng
CHINESE JOURNAL OF CATALYSIS, 2019, 40 (08) : 1141 - 1146
[7] Highly active and CO2 tolerant Ir nanocatalysts for H2/CO2 separation in electrochemical hydrogen pumps
Kim, Soo Jin
Park, Hee-Young
Ahn, Sang Hyun
Lee, Byung-seok
Kim, Hyoung-Juhn
Cho, Eunae
Henkensmeier, Dirk
Nam, Suk Woo
Kim, Sung Hyun
Yoo, Sung Jong
Jang, Jong Hyun
APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 158 : 348 - 354
[8] Recent Advances in Transition Metal Phosphide Nanocatalysts for H2 Evolution and CO2 Reduction
Shaheen, Saman
Ali, Syed Asim
Mir, Umar Farooq
Sadiq, Iqra
Ahmad, Tokeer
CATALYSTS, 2023, 13 (07)
[9] Iridium-Catalyzed Hydrocarboxylation of Olefins with CO2 and H2
Li, Yang
Wang, Ying
Zhang, Longbo
Zhang, Yanru
Guo, Jia
Wang, Yanyan
Yu, Chenglong
He, Jun
Wang, Zhenpeng
Han, Juanjuan
Li, Qian
Wu, Tianbin
Qian, Qingli
Han, Buxing
MOLECULES, 2025, 30 (07):
[10] PdGa/TiO2 an efficient heterogeneous catalyst for direct methylation of N-methylaniline with CO2/H2
Su, Xinluona
Lin, Weiwei
Cheng, Haiyang
Zhang, Chao
Li, Yan
Liu, Tong
Zhang, Bin
Wu, Qifan
Yu, Xiujuan
Zhao, Fengyu
RSC ADVANCES, 2016, 6 (105): : 103650 - 103656

← 1 2 3 4 5 →