A Simple Nickel Metal-Organic Framework-Catalyzed Borylation of Aryl Chlorides and Bromides

被引：4

作者：

Prakash, Aishwarya ^{[1
]}

Basappa, Suma ^{[1
]}

Jeebula, Bhavya ^{[1
]}

Nagaraju, Doddahalli H. ^{[2
]}

Dhayal, Rajendra S. ^{[3
]}

Bose, Shubhankar Kumar ^{[1
]}

机构：

[1] Jain Univ, Ctr Nano & Mat Sci CNMS, Bangalore 562112, India

[2] REVA Univ, Sch Appl Sci, Dept Chem, Bangalore 560064, India

[3] Cent Univ Punjab, Sch Basic & Appl Sci, Dept Chem, Bathinda 151401, India

来源：

ORGANIC LETTERS | 2024年 / 26卷 / 13期

关键词：

CROSS-COUPLING REACTIONS; HALIDES; ROUTE; ALKYL; ACTIVATION; HALOARENES;

D O I：

10.1021/acs.orglett.4c00535

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report a recyclable and efficient catalyst system based on a nickel-benzene tricarboxylic acid metal-organic framework (Ni-BTC MOF) for the borylation of aryl halides, including aryl chlorides, with bis(pinacolato)diboron, affording aryl boronate esters in high yields (up to >99% yield) with high selectivity. This protocol demonstrates broad functional group tolerance. Catalyst can be recyclable up to four times, and gram-scale reactions further highlights the usefulness of this method. In situ EPR experiments confirmed the formation of catalytically active Ni(I) species.

引用

页码：2569 / 2573

页数：5

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