Na2Ca(HPO4)2, an Efficient, Reusable Eco-Friendly Catalyst for the Synthesis of 1,8-Dioxo-Octahydroxanthenes and Biscoumarin Derivatives

被引：28

作者：

Chehab, Soukaina ^{[1
]}

Merroun, Youssef ^{[1
]}

Ghailane, Rachida ^{[1
]}

Boukhris, Said ^{[1
]}

Souizi, Abdelaziz ^{[1
]}

机构：

[1] Univ Ibn Tofail, Lab Organ Chem Catalysis & Environm, Fac Sci, POB 133, Kenitra 14000, Morocco

来源：

POLYCYCLIC AROMATIC COMPOUNDS | 2023年 / 43卷 / 06期

关键词：

Na2Ca(HPO4)(2); 1; 8-dioxo-octahydroxanthenes; biscoumarin; heterogeneous catalyst; environmentally friendly process; ONE-POT SYNTHESIS; HIGHLY EFFICIENT; SOLVENT-FREE; IONIC LIQUID; PHOSPHATE FERTILIZERS; RECYCLABLE CATALYST; GREEN SYNTHESIS; SULFONIC-ACID; NANOPARTICLES; 1,8-DIOXO-DECAHYDROACRIDINES;

D O I：

10.1080/10406638.2022.2094421

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this paper, Na2Ca(HPO4)(2) was used for the first time as a heterogeneous catalyst for efficient and green synthesis of 1,8-dioxo-octahydroxanthenes and biscoumarin derivatives. Under optimal conditions, the products were obtained with excellent yields in a short reaction time. This developed procedure has shown several advantages: avoiding toxic solvents, catalyst, simple handling, mild conditions, easy recovery, and catalyst reuse. Na2Ca(HPO4)(2) as a heterogeneous catalyst guarantees an environmentally friendly process; it can be considered an alternative to the other previously reported synthesis methods.

引用

页码：4906 / 4923

页数：18

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