Advances in heterocycle synthesis through photochemical carbene transfer reactions

被引：37

作者：

Xie, Zi-Yi ^{[1
,2
]}

Xuan, Jun ^{[1
,2
,3
]}

机构：

[1] Anhui Univ, Coll Chem & Chem Engn, Anhui Prov Key Lab Chem Inorgan Organ Hybrid Funct, Hefei 230601, Anhui, Peoples R China

[2] Anhui Univ, Coll Chem & Chem Engn, Key Lab Funct Inorgan Mat Anhui Prov, Hefei 230601, Anhui, Peoples R China

[3] Anhui Univ, Key Lab Struct & Funct Regulat Hybrid Mat, Minist Educ, Hefei 230601, Anhui, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 16期

基金：

中国国家自然科学基金;

关键词：

SEQUENTIAL VISIBLE-LIGHT; PHOTOREDOX CATALYSIS; ALPHA-SILYL; CYCLIZATION; ACYLSILANES; ALKYLATION;

D O I：

10.1039/d3cc06056j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heterocyclic skeletons are commonly found in various bioactive molecules and pharmaceutical compounds, making them crucial in areas such as medicinal chemistry, materials science, and the realm of natural product synthesis. In recent years, the rapid advancements of visible light methodologies in organic synthesis have shown promising potential for the development of light-induced carbene transfer reactions. This is particularly significant as most organic molecules do not absorb visible light. Free carbene, known for its high activity, is frequently utilized for insertion reactions or cyclopropanation reactions. This review focuses on the photochemical strategy for the construction of heterocyclic skeletons, specifically highlighting the methods that employ visible light-promoted carbene transfer reactions. In this feature article, we focus on the photochemical strategy for the construction of heterocyclic skeletons, specifically highlighting the methods that employ visible light-promoted carbene transfer reactions.

引用

页码：2125 / 2136

页数：12

共 70 条

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