Tuneable tetrel bonds between tin and heavy pnictogens

被引：5

作者：

Liyanage, Sachin ^{[1
]}

Ovens, Jeffrey S. S. ^{[1
]}

Scheiner, Steve ^{[2
]}

Bryce, David L. L. ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem & Biomol Sci, Ottawa, ON K1N 6N5, Canada

[2] Utah State Univ, Dept Chem & Biochem, Logan, UT 84322 USA

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 58期

基金：

加拿大自然科学与工程研究理事会;

关键词：

546.2 Tin and Alloys;

D O I：

10.1039/d3cc02644b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of a binary cocrystal, comprised of SnPh3Cl and PPh3, whose components are organized via short and directional tetrel bonds (TtB) between tin and phosphorus, is described. DFT elucidates, for the first time, the factors influencing the strength of TtBs involving heavy pnictogens. A CSD survey reveals that such TtBs are also present and determinative in single component molecular systems, highlighting their significant potential as tuneable structure-directing elements.

引用

页码：9001 / 9004

页数：4

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