Rhodaelectro-Catalyzed Decarboxylative Cross-Dehydrogenative Coupling of Indole-3-carboxylic Acids and Olefins via Weakly Coordinating Carboxyl Groups

被引：6

作者：

Zhang, Jiaqi ^{[1
]}

Xu, Weijie ^{[1
]}

Zhuang, Weihui ^{[1
]}

Chen, Ximan ^{[1
]}

Zhang, Xiaofeng ^{[1
]}

Huang, Qiufeng ^{[1
]}

机构：

[1] Fujian Normal Univ, Coll Chem & Mat Sci, Fujian Key Lab Polymer Mat, Fujian Prov Key Lab Adv Mat Oriented Chem Engn, Fuzhou 350007, Fujian, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 88卷 / 21期

关键词：

C-H FUNCTIONALIZATION; TRACELESS DIRECTING GROUPS; DERIVATIVES; ANNULATION; ALKYNES; CYCLIZATION; ACTIVATION; INDOLE;

D O I：

10.1021/acs.joc.3c01690

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A rhodaelectro-catalyzed C2-H selectively decarboxylative alkenylation of 3-carboxy-1H-indoles employing electricity as the traceless terminal oxidant has been accomplished. The weakly coordinating carboxyl group serves as the traceless directing groups. External oxidant-free in an undivided cell with constant current in aqueous solution ensures the decarboxylative C-H alkenylation to be viable and sustainable.

引用

页码：15198 / 15208

页数：11

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