Eco-friendly synthesis of L-Cysteine incorporated Swiss cheese-like carbon from Artocarpus heterophyllus peel waste for high performance symmetric supercapacitor

被引:5
作者
Chinnalagu, Dhilip Kumar [1 ]
Murugesan, Balaji [2 ]
Arumugam, Mayakrishnan [1 ]
Ganesan, Selvanathan [3 ]
Mahalingam, Sundrarajan [1 ]
机构
[1] Alagappa Univ, Sch Chem Sci, Dept Ind Chem, Adv Green Chem Lab, Karaikkudi 630003, Tamil Nadu, India
[2] Zhejiang Sci Tech Univ, Sch Mat Sci & Engn, Key Lab Adv Text Mat, Natl Engn Lab Text Fiber Mat & Proc Technol, Hangzhou 310018, Peoples R China
[3] AVC Coll Arts & Sci, Mayiladuthurai 609305, Tamil Nadu, India
关键词
Energy storage; L; -cysteine; Heteroatom; Trastii ' s plot; Faradic charge transfer; Semi-pseudocapacitive; HIERARCHICAL POROUS CARBON; NITROGEN-DOPED CARBON; IN-SITU SYNTHESIS; OXYGEN REDUCTION; ACTIVATED CARBON; IONIC LIQUID; GRAPHENE; ELECTRODE; STORAGE; NANOCOMPOSITES;
D O I
10.1016/j.biombioe.2023.106826
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Due to their exceptional properties, developing a new nanostructured material inspired by biomaterials is one of the most alluring topics. With the aid of L-cysteine, we synthesized a novel type of N and S-doped mesoporous carbon (NSC3) derived from Artocarpus heterophyllus peel that has a Swiss cheese-like structure. Capacitive energy storage differs from other electrochemical energy storage, which renders less charging time and delivers more power than batteries. Importantly, low energy density is considered a pivotal limitation to this technique, so considerable interest has been inducing pseudocapacitance to EDL-Capacitive material for efficient energy storage. The BET findings determined a high surface area of 1896.32 m2g-1 for NSC3 and transformation of micro to mesopore with a pore diameter of 2.86 nm from 1.92 nm with successive addition of L-cysteine. Trastii's plot delivers 36.6% as diffusion and 63.4% as EDL-Capacitive behavior for NSC3, also met the requirements of semipseudocapacitive type with an improved specific capacitance of 433Fg-1 at 1Ag-1 current density. Even at a highpower density of 6875 W kg- 1, the constructed NSC3//NSC3 symmetric device delivered an enhanced energy density of 7.84 Wh Kg-1 and maintained 88.53% of its original capacitance for 10,000 consecutive cycles.
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页数:16
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