Synthesis and Crystal Structure of the Zinc Borate Zn3B4O9

被引：5
|
作者：
Ziegler, Raimund [1 ]
Seibald, Markus [2 ]
Stoll, Christiane [2 ]
Huppertz, Hubert [1 ]
机构：
[1] Univ Innsbruck, Dept Gen Inorgan & Theoret Chem, Innrain 80-82, A-6020 Innsbruck, Austria
[2] Ams OSRAM Int GmbH, Mittelstetter Weg 2, D-86830 Schwabmunchen, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2023年 / 26卷 / 20期
关键词：
doping; high-pressure; high-temperature synthesis; luminescence; manganese; structure elucidation; BOND-VALENCE PARAMETERS; DISTRIBUTIONS;
D O I：
10.1002/ejic.202300174
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new zinc borate Zn3B4O9 was synthesized at high-pressure/high-temperature conditions of 10 GPa and 1173 K in a Walker-type multianvil pressure device. It crystallizes in the space group P 1? ${\bar{1}}$ (no. 2) with a=5.5028(2) angstrom, b=6.7150(3) angstrom, c=7.8887(3) angstrom, alpha=83.99(1)degrees, beta=73.38(1)degrees, gamma=74.75(1)degrees, V=269.35(2) angstrom(3), and two formula units (Z=2) per unit cell. The structure was confirmed via single-crystal X-ray diffraction. Zn3B4O9 can be synthesized phase pure, which is shown with a Rietveld refinement. IR-spectroscopic data of a powder sample were collected.
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页数：7
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