Gold-Catalyzed C-O Cross-Coupling Reactions of Aryl Iodides with Silver Carboxylates

被引：22

作者：

Chen, Guifang ^{[1
]}

Xu, Bo ^{[1
]}

机构：

[1] Donghua Univ, Minist Educ, Coll Chem & Chem Engn, Key Lab Sci & Technol Ecotext, Shanghai 201620, Peoples R China

来源：

ORGANIC LETTERS | 2023年 / 25卷 / 34期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/acs.orglett.3c02254

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We have developed a C-O cross-coupling reactionof (hetero)aryliodides with silver carboxylates via a Au-I/Au-III catalytic cycle. The transformation featured exclusive chemoselectivityand moisture/air insensitivity. Aromatic and aliphatic (includingprimary, secondary, and tertiary) silver carboxylates are all suitablesubstrates. Moreover, this protocol worked well intermolecularly andintramolecularly. Most importantly, good yields were obtained regardlessof the substrates' electronic effect and steric hindrance.

引用

页码：6334 / 6339

页数：6

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