Facile synthesis of a MOF-derived Co-N-C nanostructure as a bi-functional oxygen electrocatalyst for rechargeable Zn-air batteries

被引：7

作者：

Luo, Xinlei ^{[1
]}

Zheng, Ziheng ^{[1
]}

Hou, Bingxue ^{[2
]}

Xie, Xianpan ^{[1
]}

Wang, Cheng Cheng ^{[1
]}

机构：

[1] Shenzhen Polytech, Sch Entrepreneurship & Innovat, Shenzhen 518055, Peoples R China

[2] Civil Aviat Flight Univ China, Aviat Engn Inst, Guanghan 618037, Peoples R China

来源：

RSC ADVANCES | 2023年 / 13卷 / 27期

关键词：

BIFUNCTIONAL ELECTROCATALYSTS; REDUCTION REACTION; CARBON; CATALYSTS; IRON; POLYANILINE; EVOLUTION;

D O I：

10.1039/d3ra02191b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel catalyst obtained from the pyrolysis of a Co/Fe/Zn zeolitic imidazolite framework was prepared as an oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) electrocatalyst. The Co-N-C-900 catalyst displays promising ORR and OER activity with E-1/2 = 0.854 V and E-j=10 = 1.780 V. The rechargeable Zn-air battery equipped with a Co-N-C-900 cathode electrocatalyst illustrates a high peak power density of 275 mW cm(-2), which is much superior than that of commercial 20% Pt/C. Significantly, the designed Zn-air battery with the Co-N-C-900 catalyst presents good cycling stability for 180 h in the rechargeable Zn-air battery.

引用

页码：18888 / 18897

页数：10

共 50 条

[31] Facile in situ coupling CoFe/Co nanoparticles and N-doped carbon nanotubes/graphitic nanosheets as bifunctional oxygen electrocatalysts for rechargeable Zn-air batteries [J].

Zhu, Ping ;

Gao, Jingxia ;

Liu, Sa .

JOURNAL OF POWER SOURCES, 2020, 449

[32] Cu and Co nanoparticle-Co-decorated N-doped graphene nanosheets: a high efficiency bifunctional electrocatalyst for rechargeable Zn-air batteries [J].

Liu, Peitao ;

Hu, Yating ;

Liu, Xiaokai ;

Wang, Tongtong ;

Xi, Pinxian ;

Xi, Shibo ;

Gao, Daqiang ;

Wang, John .

JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (20) :12851-12858

[33] Encapsulating Cobalt Nanoparticles in Interconnected N-Doped Hollow Carbon Nanofibers with Enriched Co-N-C Moiety for Enhanced Oxygen Electrocatalysis in Zn-Air Batteries [J].

Lu, Qi ;

Wu, Han ;

Zheng, Xuerong ;

Chen, Yanan ;

Rogach, Andrey L. ;

Han, Xiaopeng ;

Deng, Yida ;

Hu, Wenbin .

ADVANCED SCIENCE, 2021, 8 (20)

[34] MOF-Derived N-Doped C @ CoO/MoC Heterojunction Composite for Efficient Oxygen Reduction Reaction and Long-Life Zn-Air Battery [J].

Yin, Ruilian ;

Ma, Suli ;

Ying, Jiaping ;

Lu, Zhentao ;

Niu, Xinxin ;

Feng, Jinxiu ;

Xu, Feng ;

Zheng, Yifan ;

Liu, Wenxian ;

Cao, Xiehong .

BATTERIES-BASEL, 2023, 9 (06)

[35] Co@C,MnO-NAC via selective wrapping for effective oxygen electrocatalysis in rechargeable Zn-air batteries [J].

Zhou, Wenshu ;

Liu, Yanyan ;

Wu, Dichao ;

Zhang, Pengxiang ;

Zhang, Gaoyue ;

Sun, Kang ;

Li, Baojun ;

Jiang, Jianchun .

SUSTAINABLE ENERGY & FUELS, 2022, 6 (03) :791-799

[36] Bifunctional electrocatalysts of MOF-derived Co-N/C on bamboo-like MnO nanowires for high-performance liquid- and solid-state Zn-air batteries [J].

Chen, Ya-Nan ;

Guo, Yibo ;

Cui, Huijuan ;

Xie, Zhaojun ;

Zhang, Xin ;

Wei, Jinping ;

Zhou, Zhen .

JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (20) :9716-9722

[37] N, P, S tri-doped hollow carbon nanosphere as a high-efficient bifunctional oxygen electrocatalyst for rechargeable Zn-air batteries [J].

Tao, Xisheng ;

Zhang, Qi ;

Li, Yan ;

Lv, Xiaoling ;

Ma, Delong ;

Wang, Heng-guo .

APPLIED SURFACE SCIENCE, 2019, 490 :47-55

[38] MOF-assisted synthesis of Ni, Co, Zn, and N multidoped porous carbon as highly efficient oxygen reduction electrocatalysts in Zn-air batteries [J].

Huang, K. ;

Rong, C. ;

Zhang, W. ;

Yang, X. ;

Fan, Y. ;

Liu, L. ;

Yang, Z. ;

Chen, W. ;

Yang, J. .

MATERIALS TODAY ENERGY, 2021, 19

[39] Facile synthesis of carbon coated cobalt-cobalt molybdenum carbide as advanced bifunctional oxygen electrocatalyst for rechargeable Zn-air battery [J].

Chen, Siru ;

Liu, Xuan ;

Sun, Han ;

Cao, Zhenyu ;

Xiong, Jiabin ;

Li, Yanqiang .

JOURNAL OF ALLOYS AND COMPOUNDS, 2022, 897

[40] Controlled synthesis of FeNx-CoNx dual active sites interfaced with metallic Co nanoparticles as bifunctional oxygen electrocatalysts for rechargeable Zn-air batteries [J].

Wu, Yi-jin ;

Wu, Xiao-hong ;

Tu, Teng-xiu ;

Zhang, Peng-fang ;

Li, Jun-tao ;

Zhou, Yao ;

Huang, Ling ;

Sun, Shi-gang .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2020, 278

← 1 2 3 4 5 →