The spatiotemporal motion characteristics of the kilowatt argon microwave plasma torch with the air carrier gas (kW-AC-ArMPT) and the behavior of the plasma filaments are investigated with a digital single-lens reflex (SLR) camera and a high-speed camera. Along with the introduction of the air, both the volume of the central channel and the rotational frequency of the plasma filament are increased. Besides, the excitation temperature (T-exc), rotational temperature (T-rot), and density of electron number (n(e)) of the kW-AC-ArMPT are measured with optical diagnosis. It is clearly shown that the introduction of air contributed to the rise of T-rot and n(e) of the plasma, which is beneficial to improving the analytical performance of the plasma. Then the detection limits of some heavy metal elements are measured by kW-AC-ArMPT, which are in the ppb range. The experimental results show that the kW-ArMPT has a high tolerance to air injection at least 1.0 L/min, which allows the direct extraction of air from the environment for analysis and therefore has the potential for online and in-situ detection of ambient air quality and industrial exhaust gases.
机构:
Univ Yamanashi, Clean Energy Res Ctr, Takeda 4, Kofu, Yamanashi 4008511, Japan
Inst Ion Plasma & Laser Technol, Durmon Yoli St 33, Tashkent 100125, UzbekistanNara Inst Sci & Technol, Dept Mat Sci, Takayama Cho 8916-5, Ikoma, Nara 6300101, Japan
Usmanov, Dilshadbek T.
Yu, Zhan
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Univ Yamanashi, Clean Energy Res Ctr, Takeda 4, Kofu, Yamanashi 4008511, Japan
Shenyang Normal Univ, Sch Chem & Life Sci, 253 Huanghe St, Shenyang 110034, Liaoning, Peoples R ChinaNara Inst Sci & Technol, Dept Mat Sci, Takayama Cho 8916-5, Ikoma, Nara 6300101, Japan
Yu, Zhan
Chen, Lee Chuin
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Univ Yamanashi, Interdisciplinary Grad Sch Med & Engn, Takeda 4, Kofu, Yamanashi 4008511, JapanNara Inst Sci & Technol, Dept Mat Sci, Takayama Cho 8916-5, Ikoma, Nara 6300101, Japan
Chen, Lee Chuin
Hiraoka, Kenzo
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Univ Yamanashi, Clean Energy Res Ctr, Takeda 4, Kofu, Yamanashi 4008511, JapanNara Inst Sci & Technol, Dept Mat Sci, Takayama Cho 8916-5, Ikoma, Nara 6300101, Japan
Hiraoka, Kenzo
Yamabe, Shinichi
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Nara Inst Sci & Technol, Dept Mat Sci, Takayama Cho 8916-5, Ikoma, Nara 6300101, JapanNara Inst Sci & Technol, Dept Mat Sci, Takayama Cho 8916-5, Ikoma, Nara 6300101, Japan
Yamabe, Shinichi
JOURNAL OF MASS SPECTROMETRY,
2016,
51
(02):
: 132
-
140
机构:
Univ Sao Paulo, Inst Quim, Dept Quim Fundamental, BR-05508000 Sao Paulo, BrazilUniv Sao Paulo, Inst Quim, Dept Quim Fundamental, BR-05508000 Sao Paulo, Brazil
Fioroto, Alexandre Minami
Rodrigues Kelmer, Gislayne Aparecida
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Univ Sao Paulo, Inst Quim, Dept Quim Fundamental, BR-05508000 Sao Paulo, BrazilUniv Sao Paulo, Inst Quim, Dept Quim Fundamental, BR-05508000 Sao Paulo, Brazil
Rodrigues Kelmer, Gislayne Aparecida
Rodrigues Albuquerque, Luiza Gimenes
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Univ Sao Paulo, Inst Quim, Dept Quim Fundamental, BR-05508000 Sao Paulo, BrazilUniv Sao Paulo, Inst Quim, Dept Quim Fundamental, BR-05508000 Sao Paulo, Brazil
Rodrigues Albuquerque, Luiza Gimenes
Longo Cesar Paixao, Thiago Regis
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Univ Sao Paulo, Inst Quim, Dept Quim Fundamental, BR-05508000 Sao Paulo, BrazilUniv Sao Paulo, Inst Quim, Dept Quim Fundamental, BR-05508000 Sao Paulo, Brazil
Longo Cesar Paixao, Thiago Regis
Oliveira, Pedro Vitoriano
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Univ Sao Paulo, Inst Quim, Dept Quim Fundamental, BR-05508000 Sao Paulo, BrazilUniv Sao Paulo, Inst Quim, Dept Quim Fundamental, BR-05508000 Sao Paulo, Brazil