Phenyliodine(III)diacetate (PIDA): Applications in Rearrangement/Migration Reactions

被引：16

作者：

Alam, M. Mujahid ^{[1
]}

Bollikolla, Hari Babu ^{[2
]}

Amanullah, Mohammed ^{[3
]}

Hussein, Mohamed ^{[1
,4
]}

Varala, Ravi ^{[5
]}

机构：

[1] King Khalid Univ, Coll Sci, Dept Chem, Abha 61413, Saudi Arabia

[2] Acharya Nagarjuna Univ, Dept Nanotechnol, Guntur 522510, Andhra Prades, India

[3] Agr Res Ctr, Cent Agr Pesticide Lab, Giza 12618, Egypt

[4] King Khalid Univ, Coll Med, Dept Clin Biochem, Abha, Saudi Arabia

[5] Scrips Pharm, Hyderabad 500076, Telangana, India

来源：

CURRENT ORGANIC CHEMISTRY | 2023年 / 27卷 / 02期

关键词：

Phenyliodine(III) diacetate (PIDA; DAIB); oxidizing agent; organic synthesis; rearrangements; migrations; mechanistic aspects; HYPERVALENT IODINE(III) REAGENTS; ONE-POT SYNTHESIS; OXIDATIVE REARRANGEMENT; MOLECULAR-STRUCTURES; (DIACETOXYIODO)BENZENE; DIACETATE; FUNCTIONALIZATION; PHI(OAC)(2); IODOARENES; AMINATION;

D O I：

10.2174/1385272827666230330105241

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

One of the most widely utilized hypervalent iodines used as an oxidizing agent in organic chemistry is (dialcetoxyiodo)benzene (PhI(OAc)(2)), also known as (DAIB), phenyliodine(III) diacetate (PIDA). In this mini-review, PIDA is highlighted in relation to its applications in organic synthesis involving rearrangement/migration reactions along with their interesting mechanistic aspects from the summer of 2015 to the present.

引用

页码：93 / 107

页数：15

共 74 条

[1] SECONDARY BONDING .13. ARYL-TELLURIUM(IV) AND ARYL-IODINE(III) ACETATES AND TRIFLUOROACETATES - THE CRYSTAL AND MOLECULAR-STRUCTURES OF BIS-(PARA-METHOXYPHENYL)TELLURIUM DIACETATE, MU-OXO-BIS[DIPHENYLTRIFLUOROACETOXYTELLURIUM] HYDRATE, AND (BIS(TRIFLUOROACETOXY)IODO]BENZENE [J].