High-entropy (La0.2Dy0.2Er0.2Yb0.2Y0.2)2Zr2O7 oxide, a potential thermal barrier coating material with photoluminescence property sensitive to pressure

In this work, high-entropy (La0.2Dy0.2Er0.2Yb0.2Y0.2)(2)Zr2O7 oxide (RZHEO-1600) has been synthesized by using a simple solid-state reaction method and investigated as a promising thermal barrier coating (TBC) material with potential optical pressure sensing application. Compared to oxide-yttria stabilized zirconium (YSZ) and single component zirconates, RZHEO-1600 exhibits excellent thermal stability at 1600 C-degrees and a larger thermal expand coefficient 13.5 x 10(-6) K-1 due to the high entropy effect. Its thermal conductivity (1.23-1.41 W m(-1) K-1) and Vickers hardness (10 GPa) are lower than YSZ, while its fracture toughness (2.9 MPa m(1/2)) is much larger. The photoluminescence (PL) emissions of RZHEO-1600 excited by 514 nm laser are assigned to S-4(3/2) -> I-4(15/2) and F-4(9/2) -> I-4(15/2) transitions of Er3+ ions. The centre positions of emission peaks initially at 560 and 677 nm are sensitive to pressure, which red shift linearly with pressure coefficients of 0.178 nm/GPa (-5.650 cm(-1)/GPa) and 0.223 nm/GPa (-4.932 cm(-1)/GPa), respectively. Interestingly, the PL intensity ratios I-677/I-658 and I-560/I-547 are found to be pressure sensitive, which continuously increase during the compression. The findings of this study could serve as a new guide for the development of novel high-entropy oxide TBC materials with optical sensing applications.