Synthesis of phenyl-based hyper-crosslinked porous organic polymers via Friedel-Crafts reaction for efficient organic dye adsorption

被引:9
作者
Zhou, Shiyuan [1 ]
Lin, Qi [1 ]
Ren, Zhongfei [1 ]
Zhou, Congsheng [1 ]
Shan, Yuhua [1 ]
Liu, Ping [1 ]
机构
[1] Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China
关键词
Friedel-Crafts reaction; Porous organic polymers; Dye adsorption; REMOVAL; CARBON; WATER; ADSORBENTS; FRAMEWORKS;
D O I
10.1016/j.micromeso.2023.112765
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Hyper-crosslinked polymers (HCPs) with high specific surface areas and porous structural characteristics serving as adsorbents are currently a hot research topic. In this paper, a series of one-step 3D structured phenyl-based hyper-crosslinked porous polymers via Friedel-Crafts reaction namely POP-TB with different feeding ratios were successfully synthesized. POP-TB exhibits excellent adsorption performance towards four organic dyes including Rhodamine B, Acid green, Reactive blue, Crystal violet and the maximum adsorption capacity (q(m)) are 1065, 2542, 1900 and 1270 mg g(-1), respectively, surpassing most of the adsorbents in previous reports.
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页数:7
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