Dataset for the experimental study of dimethyl sulfoxide as a thermodynamic inhibitor of methane hydrate formation

To determine the ability of dimethyl sulfoxide (DMSO) to inhibit methane hydrate formation by the thermodynamic mechanism, we measured the pressures and temperatures of monovariant equilibrium of three phases: gaseous methane, aqueous DMSO solution, and methane hydrate. A total of 54 equilibrium points were obtained. Hydrate equilibrium conditions have been measured for eight different concentrations of dimethyl sulfoxide ranging from 0 to 55 mass%, at temperatures of 242-289 K and pressures of 3-13 MPa. Measurements were performed in an isochoric autoclave (volume of 600 cm(3), inside diameter of 8.5 cm) at a heating rate of 0.1 K/h and intense fluid agitation (600 rpm) with four-blade impeller (diameter of 6.1 cm, blade height of 2 cm). The specified stirring speed for aqueous DMSO solutions at 273-293 K is equivalent to a range of Reynolds numbers of 5.3 center dot 10(3) -3.7 center dot 10(4). The endpoint of methane hydrate dissociation at defined temperature and pressure values was taken as the equilibrium point. The anti-hydrate activity of DMSO was analyzed on a mass% and mol% scale. Precise correlations between the thermodynamic inhibition effect of dimethyl sulfoxide Lambda T-h and the influencing factors (DMSO concentration and pressure) were derived. Powder X-ray diffractometry was employed to examine the phase composition of the samples at 153 K. Measurement of ice freezing points in aqueous solutions of dimethyl sulfoxide (up to 50 mass%) at ambient pressure allowed us to clarify the location of the liquidus line in the DMSO-H2O system and to check the hydrate equilibrium data for thermodynamic consistency. (C) 2023 The Author(s). Published by Elsevier Inc. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/)