Biomass-based porous carbon for high-performance supercapacitor electrode materials prepared from Canada goldenrod

被引:29
作者
Tu, Jianfei [1 ,2 ,3 ]
Qiao, Zhijun [1 ,2 ]
Wang, Yuzuo [1 ,2 ]
Li, Gaofeng [1 ,2 ]
Zhang, Xi [1 ,2 ]
Li, Guoping [1 ,2 ]
Ruan, Dianbo [1 ,2 ]
机构
[1] Ningbo Univ, Inst Adv Energy Storage Technol & Equipment, Ningbo 315211, Zhejiang, Peoples R China
[2] Ningbo Univ, Fac Mech Engn & Mech, Ningbo 315211, Zhejiang, Peoples R China
[3] Zhejiang Prov Hlth & Smart Kitchen Engn Res Ctr, Ningbo 315300, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
Biomass; Canada goldenrod; Supercapacitor; Activated carbon; ELECTROCHEMICAL PROPERTIES; ACTIVATED CARBONS; STORAGE;
D O I
10.1016/j.est.2023.109268
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Preparing activated carbon from biomass materials that can be used as electrode materials for supercapacitors is crucial for realizing new green energy storage and conversion technologies to fulfill environmental requirements. Herein, activated carbon was prepared via high-temperature carbonization and KOH activation using Canada goldenrod as a raw material, which is a serious threat to the ecological environment. Using this activated carbon as the active material and 6 M KOH and 1 M TEABF4/AN as the electrolytes, aqueous and organic coin-cell symmetrical supercapacitors were prepared, respectively. The specific capacitance of activated carbon was calculated to reach 320 and 123 F/g at a current density of 0.1 A/g during its testing in a two-electrode system, corresponding to energy densities of 40 and 112.1 Wh/kg, respectively. The power density of the aqueous supercapacitor was 9 KW/Kg at 10 A/g, while that of the organic supercapacitor was 12.2 KW/Kg at 5 A/g; after 10,000 cycles of the charge-discharge test, the capacity retention rate reached 93.6 % and 86.4 %, indicating the excellent electrochemical performance of the prepared supercapacitor. In addition, the specific capacitance reached 366 and 252 F/g at capacitance densities of 0.1 and 0.5 A/g, respectively, during its testing in a threeelectrode system. The results of this study indicate that Canada goldenrod is a good biomass-based precursor material for preparing porous carbon for supercapacitors.
引用
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页数:13
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