Broadband Near-Infrared Luminescence in Garnet Y3Ga3MgSiO12: Cr3+ Phosphors

被引:65
作者
Jiang, Lipeng [1 ]
Jiang, Xue [1 ]
Zhang, Liangliang [2 ]
Liu, Quansheng [3 ]
Mi, Xiaoyun [3 ]
Yu, Zhan [4 ]
Lv, Guocai [5 ]
Su, Yanjing [1 ]
机构
[1] Univ Sci & Technol Beijing, Beijing Adv Innovat Ctr Mat Genome Engn, Corros & Protect Ctr, Beijing 100083, Peoples R China
[2] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, State Key Lab Luminescence & Applicat, Changchun 130033, Peoples R China
[3] Changchun Univ Sci & Technol, Sch Mat Sci & Engn, Changchun 130022, Peoples R China
[4] Zhongguancun Key Lab Solid State Lighting, Beijing 100083, Peoples R China
[5] Univ Sci & Technol Beijing, Basic Expt Ctr Nat Sci, Beijing 100083, Peoples R China
关键词
EFFICIENT;
D O I
10.1021/acs.inorgchem.2c04319
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Broadband near-infrared (NIR) phosphors are the critical component of phosphor converted NIR light-emitting diode (LED) light sources. However, there are still a lack of NIR phosphors with excellent external quantum efficiency (EQE) and thermal stability. Here, we report a highly efficient broadband NIR phosphor Y3Ga3MgSiO12: Cr3+. The optimized phosphor yields an internal quantum efficiency (IQE) and an EQE of 79.9 and 33.7%, respectively. The integrated emission intensity still remains at 84.4% of that at room temperature when heated to 423 K. A broadband NIR LED lamp was made by combining as-prepared phosphor and a blue InGaN LED chip, which shows an output power of 89.8 mW with a photoelectric conversion efficiency of 17.1% driven at 525 mW input power. Our research provides a promising NIR phosphor with high efficiency broadband for the NIR light source.
引用
收藏
页码:4220 / 4226
页数:7
相关论文
共 45 条
[31]   Relationship between tertiary amine's physical property and biphasic solvent's CO2 absorption performance: Quantum calculation and experimental demonstration [J].
Yu, Yanan ;
Shen, Yao ;
Zhou, Xiaowei ;
Liu, Fan ;
Zhang, Shihan ;
Lu, Shijian ;
Ye, Jiexu ;
Li, Sujing ;
Chen, Jianmeng ;
Li, Wei .
CHEMICAL ENGINEERING JOURNAL, 2022, 428
[32]   Efficient and Broadband LiGaP2O7:Cr3+ Phosphors for Smart Near-Infrared Light-Emitting Diodes [J].
Yuan, Chenxu ;
Li, Ruiyang ;
Liu, Yongfu ;
Zhang, Liangliang ;
Zhang, Jiahua ;
Leniec, Grzegorz ;
Sun, Peng ;
Liu, Zehua ;
Luo, Zhaohua ;
Dong, Rui ;
Jiang, Jun .
LASER & PHOTONICS REVIEWS, 2021, 15 (11)
[33]   Two-Site Occupation for Exploring Ultra-Broadband Near-Infrared Phosphor-Double-Perovskite La2MgZrO6:Cr3+ [J].
Zeng, Huatao ;
Zhou, Tianliang ;
Wang, Le ;
Xie, Rong-Jun .
CHEMISTRY OF MATERIALS, 2019, 31 (14) :5245-5253
[34]   Efficient and Thermally Stable Broad-Band Near-Infrared Emission in a KAlP2O7:Cr3+ Phosphor for Nondestructive Examination [J].
Zhang, Hongshi ;
Zhong, Jiyou ;
Du, Fu ;
Chen, Lei ;
Zhang, Xiaoli ;
Mu, Zhongfei ;
Zhao, Weiren .
ACS APPLIED MATERIALS & INTERFACES, 2022, 14 (09) :11663-11671
[35]   Cr3+-Doped Broadband NIR Garnet Phosphor with Enhanced Luminescence and its Application in NIR Spectroscopy [J].
Zhang, Liangliang ;
Wang, Dandan ;
Hao, Zhendong ;
Zhang, Xia ;
Pan, Guo-hui ;
Wu, Huajun ;
Zhang, Jiahua .
ADVANCED OPTICAL MATERIALS, 2019, 7 (12)
[36]   A high efficiency broad-band near-infrared Ca2LuZr2Al3O12:Cr3+ garnet phosphor for blue LED chips [J].
Zhang, Liangliang ;
Zhang, Sheng ;
Hao, Zhendong ;
Zhang, Xia ;
Pan, Guo-hui ;
Luo, Yongshi ;
Wu, Huajun ;
Zhang, Jiahua .
JOURNAL OF MATERIALS CHEMISTRY C, 2018, 6 (18) :4967-4976
[37]   Two Selective Sites Control of Cr3+-Doped ABO4 Phosphors for Tuning Ultra-Broadband Near-Infrared Photoluminescence and Multi-Applications [J].
Zhang, Qianqian ;
Liu, Dongjie ;
Dang, Peipei ;
Lian, Hongzhou ;
Li, Guogang ;
Lin, Jun .
LASER & PHOTONICS REVIEWS, 2022, 16 (02)
[38]   Enhancing and tuning broadband near-infrared (NIR) photoluminescence properties in Cr3+-doped Ca2YHf2Al3O12 garnet phosphors via Ce3+/Yb3+-codoping for LED applications [J].
Zhang, Qianqian ;
Li, Guogang ;
Dang, Peipei ;
Liu, Dongjie ;
Huang, Dayu ;
Lian, Hongzhou ;
Lin, Jun .
JOURNAL OF MATERIALS CHEMISTRY C, 2021, 9 (14) :4815-4824
[39]   Advances in Chromium-Activated Phosphors for Near-Infrared Light Sources [J].
Zhao, Fangyi ;
Song, Zhen ;
Liu, Quanlin .
LASER & PHOTONICS REVIEWS, 2022, 16 (11)
[40]   Cr3+-Doped double perovskite antimonates: efficient and tunable phosphors from NIR-I to NIR-II [J].
Zhao, Meng ;
Liu, Shengqiang ;
Cai, Hao ;
Zhao, Fangyi ;
Song, Zhen ;
Liu, Quanlin .
INORGANIC CHEMISTRY FRONTIERS, 2022, 9 (18) :4602-4607