Selective and sensitive simultaneous detection of tartrazine and Hg2+based on N-doped yellow-green fluorescent carbon dots

被引:12
|
作者
Yuan, Lin [1 ]
Jiang, Lei [1 ]
Liu, Ze [1 ]
Xiang, Yingying [2 ]
Song, Fei [3 ]
Tu, Yujiao [1 ]
机构
[1] Kunming Univ, Sch Chem & Chem Engn, Yunnan Key Lab Food Safety Testing Technol, Yunnan Key Lab Met Organ Mol Mat & Device, Kunming 650214, Peoples R China
[2] Kunming Med Univ, Yanan Hosp, Dept Stomatol, Kunming 650031, Peoples R China
[3] Kunming Med Univ, Dept Minimally Invas Intervent, Affiliated Hosp 3, Kunming 650118, Peoples R China
关键词
Tartrazine; Hg2+; Inner filter effect; Static quenching; Carbon dots; QUANTUM DOTS; FOOD; HG2+; PROBE; NANOSHEETS; AMARANTH; ION;
D O I
10.1016/j.dyepig.2022.110893
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Tartrazine preferred in food and textile industries, but excessive consumption threats human health. Due to toxicity, non-biodegradability, and trace accumulation in the food chains, Hg2+ has attracted people's attention. Thus, it is important to detect tartrazine and Hg2+ with sensitivity way. Using VB2 and citrate as precursors, yellow-green fluorescent carbon dots were prepared by hydrothermal method. The N-CDs were purified by dialysis, thin layer chromatography and chromatographic column. Excellent linear ranges of 0.25-5 mu M and 5-50 mu M of tartrazine were obtained with low detection limits 34.98 nM, while good linear ranges of 0.25-5 mu M and 10-50 mu M of Hg2+ with low detection limits 29.64 nM, respectively. In addition, the quenching mechanisms of targets to the fluorescent of N-CDs were illuminated. Furthermore, the nanoprobe was efficiently applied to determine the content of tartrazine in carbonated drink, fruit jelly and sugar samples, and Hg2+ in tap water, lake water, and river water samples. It showed great potential to detect tartrazine and Hg2+.
引用
收藏
页数:7
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