Preparation of exposed (001) facets TiO2/Ti3C2 MXene and performance of near infrared light photodegradation

被引:10
作者
Wang, Yong [1 ]
Tan, Guoqiang [1 ]
Feng, Shuaijun [1 ]
Liu, Yun [2 ]
Liu, Wenlong [2 ]
Xia, Ao [1 ]
Ren, Huijun [3 ]
Lv, Long [4 ]
机构
[1] Shaanxi Univ Sci Technol, Sch Mat Sci & Engn, Shaanxi Key Lab Green Preparat & Functionalizat I, Xian 710021, Peoples R China
[2] Shaanxi Univ Sci Technol, Sch Elect Informat & Artificial Intelligence, Xian 710021, Peoples R China
[3] Shaanxi Univ Sci Technol, Sch Arts & Sci, Xian 710021, Peoples R China
[4] China Acad Space Technol, Xian 710100, Peoples R China
基金
中国国家自然科学基金;
关键词
(001)TiO2/Ti3C2 MXene; Local surface plasmon resonance; Near infrared light degradation; Tetracycline; PHOTOCATALYTIC DEGRADATION; TI3C2; ADSORPTION;
D O I
10.1016/j.ceramint.2022.10.157
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The (001)TiO2/Ti3C2 MXene heterojunction photocatalyst was prepared with the hydrothermal oxidation method by using the two-dimensional Ti3C2 MXene as the substrate. The formation of TiO2 surface hetero-junctions, Schottky junctions at the interface between (001) facets TiO2 and Ti3C2 MXene, and the local surface plasmon resonance effect of plasma Ti3C2 MXene combine together to promote the effective separation of electrons and holes after photoexcitation. After 150 min of near infrared light irradiation and sunlight irradiation, the degradation rates of tetracycline by (001)TiO2/Ti3C2 MXene photocatalyst are 28.63% and 52.74%, respectively, with near infrared light and full spectrum degradation characteristics. Our work is expected to provide a valuable reference for the design of MXene based full spectrum photocatalysts.
引用
收藏
页码:7258 / 7265
页数:8
相关论文
共 25 条
[1]   2D-layered Ti3C2/TiO2 hybrids derived from Ti3C2 MXenes for enhanced electromagnetic wave absorption [J].
Fan, Bingbing ;
Shang, Siyang ;
Dai, Binzhou ;
Zhao, Biao ;
Li, Ning ;
Li, Mingqiang ;
Zhang, Lianji ;
Zhang, Rui ;
Marken, Frank .
CERAMICS INTERNATIONAL, 2020, 46 (10) :17085-17092
[2]   Enhanced photocatalytic activity and mechanism of Ti3C2 - OH/Bi2WO6:Yb3+, Tm3+ towards degradation of RhB under visible and near infrared light irradiation [J].
Fang, Hongjun ;
Pan, Yusong ;
Yin, Minyuan ;
Pan, Chengling .
MATERIALS RESEARCH BULLETIN, 2020, 121 (121)
[3]   Hydrothermal synthesis of TiO2/Ti3C2 nanocomposites with enhanced photocatalytic activity [J].
Gao, Yupeng ;
Wang, Libo ;
Zhou, Aiguo ;
Li, Zhengyang ;
Chen, Jingkuo ;
Bala, Hari ;
Hu, Qianku ;
Cao, Xinxin .
MATERIALS LETTERS, 2015, 150 :62-64
[4]   Pyrolysis and reutilization of plant residues after phytoremediation of heavy metals contaminated sediments: For heavy metals stabilization and dye adsorption [J].
Gong, Xiaomin ;
Huang, Danlian ;
Liu, Yunguo ;
Zeng, Guangming ;
Wang, Rongzhong ;
Wei, Jingjing ;
Huang, Chao ;
Xu, Piao ;
Wan, Jia ;
Zhang, Chen .
BIORESOURCE TECHNOLOGY, 2018, 253 :64-71
[5]   One-step in-situ preparation of N-doped TiO2@C derived from Ti3C2 MXene for enhanced visible-light driven photodegradation [J].
Huang, Huoshuai ;
Song, Yun ;
Li, Najun ;
Chen, Dongyun ;
Xu, Qingfeng ;
Li, Hua ;
He, Jinghui ;
Lu, Jianmei .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2019, 251 :154-161
[6]   Photocatalytic Applications of Two-Dimensional Ti3C2 MXenes: A Review [J].
Huang, Kelei ;
Li, Chunhu ;
Li, Haozhi ;
Ren, Guangmin ;
Wang, Liang ;
Wang, Wentai ;
Meng, Xiangchao .
ACS APPLIED NANO MATERIALS, 2020, 3 (10) :9581-9603
[7]   MXene Ti3C2: An Effective 2D Light-to-Heat Conversion Material [J].
Li, Renyuan ;
Zhang, Lianbin ;
Shi, Le ;
Wang, Peng .
ACS NANO, 2017, 11 (04) :3752-3759
[8]   Preparation of Ti3C2 and Ti2C MXenes by fluoride salts etching and methane adsorptive properties [J].
Liu, Fanfan ;
Zhou, Aiguo ;
Chen, Jinfeng ;
Jin, Jia ;
Zhou, Weijia ;
Wang, Libo ;
Hu, Qianku .
APPLIED SURFACE SCIENCE, 2017, 416 :781-789
[9]   In situ synthesis of exfoliation TiO2@C hybrids with enhanced photocatalytic hydrogen evolution activity [J].
Liu, Jie ;
Kong, Xiangchen ;
Li, Yuanyuan ;
Zhu, Shengli ;
Liang, Yanqin ;
Li, Zhaoyang ;
Wu, Shuilin ;
Chang, Chuntao ;
Cui, Zhenduo ;
Yang, Xianjin .
APPLIED SURFACE SCIENCE, 2020, 530
[10]   Progress in Black Titania: A New Material for Advanced Photocatalysis [J].
Liu, Xiangye ;
Zhu, Guilian ;
Wang, Xin ;
Yuan, Xiaotao ;
Lin, Tianquan ;
Huang, Fuqiang .
ADVANCED ENERGY MATERIALS, 2016, 6 (17)