Ir-Catalyzed Transfer Hydrogenation and Alkylation of Aldehydes and Ketones Using Ethanol as the Hydrogen Source

被引：2
作者：
Yadav, Suman [1 ]
Rao Kuram, Malleswara [1 ,2 ]
机构：
[1] Cent Drug Res Inst, Med & Proc Chem Div, CSIR, Lucknow 226031, India
[2] Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, India
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2023年
关键词：
alkylation; ethanol; ketones; reduction; transfer hydrogenation; ASYMMETRIC TRANSFER HYDROGENATION; ALPHA-ALKYLATION; CONJUGATE REDUCTION; PRIMARY ALCOHOLS; N-ALKYLATION; LIGANDS; METHANOL; COMPLEX; MILD; ALKYNES;
D O I：
10.1002/ejoc.202201344
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Bio-derived ethanol is a promising green and sustainable hydrogen-donor solvent. Herein, we have developed Ir-catalyzed transfer hydrogenation of ketones and aldehydes using ethanol as a hydrogen source with amides as simple ligands. Furthermore, the alkylation of ketones and tandem alkylation/transfer hydrogenation of acetophenones is reported with ethanol.
引用
收藏
页数：6
相关论文
共 50 条
  • [21] Methanol as Hydrogen Source: Transfer Hydrogenation of Aldehydes near Room Temperature
    Chen, Zhenyu
    Chen, Guanhong
    Aboo, Ahmed H.
    Iggo, Jonathan
    Xiao, Jianliang
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2020, 9 (08) : 1174 - 1178
  • [22] Pd/C catalyzed transfer hydrogenation of pyrolysis oil using 2-propanol as hydrogen source
    Shafaghat, Hoda
    Lee, In-Gu
    Jae, Jungho
    Jung, Sang-Chul
    Park, Young-Kwon
    CHEMICAL ENGINEERING JOURNAL, 2019, 377
  • [23] Autocatalytic Role of Molecular Hydrogen in Copper-Catalyzed Transfer Hydrogenation of Ketones
    De Vrieze, Jenoff E.
    Blanco, Cesar A. Urbina
    Thybaut, Joris W.
    Saeys, Mark
    ACS CATALYSIS, 2019, 9 (09): : 8073 - 8082
  • [24] Pd-Catalyzed Transfer Hydrogenation of Alkenes Using Tetrahydroxydiboron as the Sole Hydrogen Donor
    Yaghoubi, Mahshid
    Reyes, Isabella C.
    Stokes, Benjamin J.
    SYNOPEN, 2024, 08 (03): : 169 - 172
  • [25] Efficient Transfer Hydrogenation of Ketones using Methanol as Liquid Organic Hydrogen Carrier
    Garg, Nidhi
    Paira, Soumen
    Sundararaju, Basker
    CHEMCATCHEM, 2020, 12 (13) : 3472 - 3476
  • [26] Radical Cyclizations Terminated by Ir-Catalyzed Hydrogen Atom Transfer
    Gansaeuer, Andreas
    Otte, Matthias
    Shi, Lei
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (03) : 416 - 417
  • [27] Alternative Hydrogen Source for Asymmetric Transfer Hydrogenation in the Reduction of Ketones
    Wakeham, Russell J.
    Morris, James A.
    Williams, Jonathan M. J.
    CHEMCATCHEM, 2015, 7 (24) : 4039 - 4041
  • [28] Ruthenium-Catalyzed Chemoselective Olefin Transfer Hydrogenation of alpha, beta-Unsaturated Carbonyl Systems By Using EtOH as Hydrogen Source
    Beaufils, Alicia
    Albrecht, Martin
    CHEMCATCHEM, 2024,
  • [29] One-pot reductive amination of carbonyl compounds and nitro compounds via Ir-catalyzed transfer hydrogenation
    Luo, Renshi
    Tong, Jinghui
    Ouyang, Lu
    Liu, Liang
    Liao, Jianhua
    RSC ADVANCES, 2023, 13 (42) : 29607 - 29612
  • [30] Manganese catalyzed asymmetric transfer hydrogenation of ketones
    Zhang, Guang-Ya
    Ruan, Sun-Hong
    Li, Yan-Yun
    Gao, Jing-Xing
    CHINESE CHEMICAL LETTERS, 2021, 32 (04) : 1415 - 1418
12345